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- W4386770810 abstract "This chapter discusses the Tolman cone angle. It explains that the properties of ligands are determined not only by their electronic properties but also their steric requirements; the Tolman cone angle concept represents then an attempt to put these steric effects on a more quantitative basis. For complexes of organophosphine ligands, the space occupied by the ligand is estimated on the basis of the imaginary cone which radiates from the metal and just touches the Van der Waals surfaces of the hydrogen atoms on the surface of the ligand. The chapter notes that the methodology may be extended to other commonly used ligands and the substituents in a phosphine ligand do not define a perfect cone. Then, it clarifies that the Tolman angle depends on the relative orientations of the rings or alkyl groups and therefore may vary from complex to complex." @default.
- W4386770810 created "2023-09-16" @default.
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- W4386770810 date "1998-09-10" @default.
- W4386770810 modified "2023-09-27" @default.
- W4386770810 title "Tolman cone angle" @default.
- W4386770810 doi "https://doi.org/10.1093/hesc/9780198559184.003.0012" @default.
- W4386770810 hasPublicationYear "1998" @default.
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