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- W4386772364 abstract "This chapter focuses on the oxidative-addition reaction of alkyl halides, wherein there is a simultaneous increase in the formal oxidation state of the metal and in its coordination number. It highlights the important aspect of the oxidative-addition reaction, which provides that ‘oxidative-addition’ does not describe the mechanism of a reaction but is just a stoichiometric definition of the result of the reaction. It also reviews the simple interaction between a metal site and an alkyl halide, which results in the oxidative-addition of the latter as the metal site acts as a nucleophile with respect to the carbon centre. The chapter discusses the analogous oxidative-addition reactions of H<sub>2</sub>. It looks at two different geometries for the transition state of the reaction with RX that have different stereochemical consequences on the reaction in relation to the alkyl group and metal site." @default.
- W4386772364 created "2023-09-16" @default.
- W4386772364 creator A5073357045 @default.
- W4386772364 date "1993-12-02" @default.
- W4386772364 modified "2023-09-27" @default.
- W4386772364 title "The oxidative-addition reaction" @default.
- W4386772364 doi "https://doi.org/10.1093/hesc/9780198557463.003.0009" @default.
- W4386772364 hasPublicationYear "1993" @default.
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