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- W4386772742 abstract "This chapter discusses the ideal diatomic gas in terms of the vibrational partition function. It explains that the value of the vibrational partition function at 300K is imperceptibly different from unity. It states that this approximation can be applied to light molecules. The chapter uses the diatomic SHO model as a reference to classical vibrational frequency. It highlights that vibrational energy levels in diatomic molecules are always non-degenerate. This should be taken into consideration when handling polyatomic species. Additionally, the chapter discusses high-temperature limiting behaviour, the canonical partition function, zero-point energy, heat capacity, and entropy in relation to the vibrational partition function. It also lists other immediate forms of rotational or vibrational motion, such as torsional oscillation, internal rotation, and free rotation." @default.
- W4386772742 created "2023-09-16" @default.
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- W4386772742 date "2017-06-08" @default.
- W4386772742 modified "2023-09-27" @default.
- W4386772742 title "The ideal diatomic gas: the vibrational partition function" @default.
- W4386772742 doi "https://doi.org/10.1093/hesc/9780198777489.003.0012" @default.
- W4386772742 hasPublicationYear "2017" @default.
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