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- W4386772783 abstract "This chapter assesses other ionic equilibria. Many ionic equilibria can be described through formalisms similar to that used for acid-base phenomena. The chapter briefly illustrates this, without going into detail. The successive complexation of metal ions by ligands has many feature in common with the stepwise protonation bases. However, there is one difference: the formation of metal-ligand complexes is typically described in terms of formation constants rather than ligand dissociation constants, where the latter would be the direct analogues of acid dissociation constants. The chapter then looks at the process of extraction, in which a given species is distributed over two contacting fluid phases. The extraction of metal ions often exploits their complexation equilibria, especially the much greater solubility in a non-polar organic phase of neutral over charged complexes. The chapter also considers solubility problems, precipitation titrations, and redox equilibria." @default.
- W4386772783 created "2023-09-16" @default.
- W4386772783 creator A5046810886 @default.
- W4386772783 date "1999-11-04" @default.
- W4386772783 modified "2023-09-27" @default.
- W4386772783 title "Other ionic equilibria" @default.
- W4386772783 doi "https://doi.org/10.1093/hesc/9780198506171.003.0005" @default.
- W4386772783 hasPublicationYear "1999" @default.
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