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- W4386773386 abstract "This chapter focuses on competing reactions in homogeneous systems. In process development, a good yield is often key to obtaining satisfactory material costs, purity, and robust operation. The essence of obtaining a good chemical yield is the understanding and control of those processes which compete with the desired reaction. This understanding is necessary to obtain a satisfactory laboratory process and, even more so, to scale-up the process for manufacture. The chapter then identifies the types of competing reaction. A pre-requisite for minimisation of side reactions is to know what they are. The commonest parameters used to manipulate absolute and relative reactivities are concentration, order of reactant addition, and temperature. The chapter also considers parallel/consecutive reactions; pH-rate and selectivity profiles; and methods for predicting reactivity." @default.
- W4386773386 created "2023-09-16" @default.
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- W4386773386 date "2000-01-20" @default.
- W4386773386 modified "2023-09-27" @default.
- W4386773386 title "Competing reactions in homogeneous systems" @default.
- W4386773386 doi "https://doi.org/10.1093/hesc/9780198503729.003.0004" @default.
- W4386773386 hasPublicationYear "2000" @default.
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