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- W4386774659 abstract "This chapter demonstrates the phase diagrams of pure substances. The phase diagram of a substance is a map showing the conditions of temperature and pressure at which its various phases are thermodynamically most stable. The boundaries between regions in a phase diagram, which are called phase boundaries, show the values of <italic>p</italic> (pressure) and <italic>T</italic> (temperature) at which the two neighbouring phases are in equilibrium. The pressure of the vapour in equilibrium with its condensed phase is called the vapour pressure of the substance. The chapter then looks at how the slope of a phase boundary is given by the Clapeyron equation, and how the slope of the liquid–vapour phase boundary is given by the Clausius–Clapeyron equation. It also considers the boiling temperature and the normal boiling point; the freezing temperature; the critical temperature; the critical pressure; and the phase rule." @default.
- W4386774659 created "2023-09-16" @default.
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- W4386774659 date "2016-12-15" @default.
- W4386774659 modified "2023-09-27" @default.
- W4386774659 title "Phase diagrams of pure substances" @default.
- W4386774659 doi "https://doi.org/10.1093/hesc/9780198727873.003.0019" @default.
- W4386774659 hasPublicationYear "2016" @default.
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