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- W4386775319 abstract "This chapter assesses the reactivity of macrocyclic complexes. It looks at axial substitution reactions and reactions of the coordinated macrocyclic ligand. The chapter also considers demetallation and metal exchange reactions, as well as metal-centred oxidation and reduction reactions. Finally, the chapter covers ligand-centred redox processes. Numerous examples are known in which macrocyclic ligands undergo this type of redox process. Direct hydrogenation reactions of both free ligands and metal complexes are possible, although reactions of the free ligands are perhaps more common. Oxidation of a coordinated macrocyclic ligand is also a more commonly observed process, and it is convenient to distinguish between oxidation processes which involve the addition of oxygen atoms and those which involve the loss of hydrogen atoms." @default.
- W4386775319 created "2023-09-16" @default.
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- W4386775319 date "1999-01-28" @default.
- W4386775319 modified "2023-09-27" @default.
- W4386775319 title "Reactivity of macrocyclic complexes" @default.
- W4386775319 doi "https://doi.org/10.1093/hesc/9780198556923.003.0006" @default.
- W4386775319 hasPublicationYear "1999" @default.
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