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- W4386777307 abstract "This chapter reviews the addition of HX to C=C, the mechanisms of the reactions of HCI HBr, H2O addition to ethene and propene, carbocations, and cationic polymerization. It discusses the mechanism and stereochemistry of the addition of X<sub>2</sub> and XY to C=C and addition to ethene and propene. It also examines the electrophilic aromatic substitution reactions, which includes aromatic compounds, halogenation, nitration, and acylation. The chapter highlights the crowding around the central carbon atom, wherein the larger C-C-C angle in the secondary carbocation keeps the other two carbon atoms further apart than they are in the primary carbocation. It talks about the electron-releasing inducive effect of two alkyl groups on the C<sup>+</sup> that favours the secondary C<sup>+</sup>." @default.
- W4386777307 created "2023-09-16" @default.
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- W4386777307 date "2000-11-23" @default.
- W4386777307 modified "2023-09-27" @default.
- W4386777307 title "Reactions with electrophiles" @default.
- W4386777307 doi "https://doi.org/10.1093/hesc/9780198505839.003.0005" @default.
- W4386777307 hasPublicationYear "2000" @default.
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