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- W4386779503 abstract "This chapter discusses the stereochemistry of reactions. A reaction involves the making and breaking of bonds, and this comes about by the interaction of one species with another, such as addition of a nucleophile to a carbonyl group. Bond formation occurs by the interaction of electrons and orbitals of both components. When two such components interact, in principle all the electrons and orbitals in each will interact to some extent. The two most important types of orbitals in analysing reactions in organic chemistry are σ bonds, π bonds, and their respective antibonding orbitals. The chapter then considers C–C σ bonding and antibonding orbitals. It also looks at orbital interactions and reactions, as well as the stereoelectronics of some common reactions." @default.
- W4386779503 created "2023-09-16" @default.
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- W4386779503 date "1998-04-23" @default.
- W4386779503 modified "2023-09-27" @default.
- W4386779503 title "Stereochemistry of reactions" @default.
- W4386779503 doi "https://doi.org/10.1093/hesc/9780198559573.003.0002" @default.
- W4386779503 hasPublicationYear "1998" @default.
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