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- W4386783123 abstract "This chapter looks at the ideal diatomic gas in relation to the rotational partition function. It explains how rotational motion is restricted to certain values of the available energy, and molecules thus have access to a manifold of quantized rotational energy levels. The chapter discusses rigid rotor assumptions and continuum approximation as a test of validity. Heteronuclear diatomic molecules do not have a symmetry and must rotate through 360° before reaching an indistinguishable state. However, it is important to recognize the existence of rotational indistinguishability for symmetrical molecules. Additionally, the chapter looks at the origin of the symmetry factor. It uses equation diagrams of the standard toolkit functions to look into rotational energy, heat capacity, and entropy." @default.
- W4386783123 created "2023-09-16" @default.
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- W4386783123 date "2017-06-08" @default.
- W4386783123 modified "2023-09-27" @default.
- W4386783123 title "The ideal diatomic gas: the rotational partition function" @default.
- W4386783123 doi "https://doi.org/10.1093/hesc/9780198777489.003.0010" @default.
- W4386783123 hasPublicationYear "2017" @default.
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