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- W4386783165 abstract "This chapter explores how internal rotations about single bonds cause some molecules to be flexible rather than to have single fixed shapes. It recalls that four single bonds radiate in tetrahedral directions from a saturated (sp3-hybridized) carbon atom, which leads to organic molecules having three-dimensional structures. The chapter then argues that molecules are not rigid because molecular vibrations cause bond lengths and bond angles to be oscillating constantly about their average values. The chapter then shifts to examine what causes strain in a molecule, and how molecular strain affects the three-dimensional shape of a molecule. It employs several methods to represent the three-dimensional structures of organic molecules in two dimensions, which help us to generate mental images of three-dimensional shapes of organic molecules, and hence better understand stereochemical aspects of organic chemistry. The chapter concludes by discussing conformations of alkanes and cycloalkanes, as well as <italic>cis-trans</italic> Isomerism in cycloalkanes." @default.
- W4386783165 created "2023-09-16" @default.
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- W4386783165 date "2013-11-07" @default.
- W4386783165 modified "2023-09-27" @default.
- W4386783165 title "Conformation and Strain in Molecules" @default.
- W4386783165 doi "https://doi.org/10.1093/hesc/9780199693276.003.0004" @default.
- W4386783165 hasPublicationYear "2013" @default.
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