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- W4386784241 abstract "This chapter discusses alkene complexes. Alkene (olefin) complexes now exist of every transition metal and constitute one of the most important classes of coordination compounds. The development of the organometallic chemistry of olefins is closely connected with the rise of the petrochemical industry during the course of this century; olefins, in particular ethylene, are abundantly available from petrochemical feedstocks. The chapter then details the synthesis of alkene complexes and bonding of alkenes to transition metals. Olefins bind to transition metals via their π orbitals, by donating electron density into an empty metal <italic>d</italic>-orbital. However, since olefins are weak bases, the bond has to be stabilized by another bonding contribution: the donation of electron density from the metal to the olefin. Finally, the chapter explains the reactivity of alkene complexes." @default.
- W4386784241 created "2023-09-16" @default.
- W4386784241 creator A5039536225 @default.
- W4386784241 date "1994-03-17" @default.
- W4386784241 modified "2023-09-27" @default.
- W4386784241 title "Alkene complexes" @default.
- W4386784241 doi "https://doi.org/10.1093/hesc/9780198558132.003.0002" @default.
- W4386784241 hasPublicationYear "1994" @default.
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