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- W4386785102 abstract "This chapter analyses the principles that explain the electronic structures of diatomic molecules and those carried across larger molecules. It reviews how molecular-orbitals can be constructed from linear combinations of atomic orbitals, wherein the total electronic wave function is antisymmetrized in order to take account of the Pauli principle. It also illustrates a molecular-orbital diagram that can be qualitatively corrected by using just the atomic orbitals that are occupied in separate atoms. The chapter looks at descriptions of molecular symmetry that can be formalized by using group theory, which is useful in describing the structures of complex molecules. It discusses the origin of the notation that is often used to describe molecular-orbitals and electronic states." @default.
- W4386785102 created "2023-09-16" @default.
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- W4386785102 date "1994-12-29" @default.
- W4386785102 modified "2023-09-27" @default.
- W4386785102 title "Polyatomic molecules" @default.
- W4386785102 doi "https://doi.org/10.1093/hesc/9780198558040.003.0003" @default.
- W4386785102 hasPublicationYear "1994" @default.
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