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- W4386820797 abstract "To provide a mechanistic understanding of the stability of the M23C6 phase under irradiation, the crystalline to amorphous (c-a) transition behavior in bulk M23C6 specimens with a variation in tungsten (W) content subjected to helium ion irradiation was investigated. The Cr-W-C ternary ingots with a W concentration range of 0-11.6 at.% were fabricated by vacuum-induced furnace melting. Microstructure characterization revealed that the dominant phase in the ingots was M23C6 regardless of the W concentration, and a small amount of metallic-Cr, (Cr, W), and W-rich carbide co-existed as the minor phase. The lattice parameter of M23C6 increases with an increase in W concentration, and the maximum value is 1.083 nm when the W content is 11.6 at.%. Based on this, the chemical formula of the M23C6 particle in F82H steel was represented by Cr20W3C6 or Cr19W4C6 because its lattice parameter was estimated to be 1.08-1.09 nm. From the grazing incident X-ray diffraction analysis before and after irradiation, the amorphous peak was only observed in the specimen of W concentration 11.6 at.% after irradiation, which was further confirmed by transmission electron microscopy analyses. It is clarified that the c-a transition behavior in M23C6 is dependent on the W content, the amorphization of M23C6 can be mitigated when the W concentration is 6.8 at.% or less under the present study condition." @default.
- W4386820797 created "2023-09-19" @default.
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- W4386820797 date "2023-12-01" @default.
- W4386820797 modified "2023-10-14" @default.
- W4386820797 title "Effect of solid solution tungsten on the radiation-induced amorphization in bulk M23C6 fabricated by vacuum induction melting" @default.
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- W4386820797 doi "https://doi.org/10.1016/j.jnucmat.2023.154740" @default.
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