Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386851059> ?p ?o ?g. }
- W4386851059 abstract "Abstract Metal–organic frameworks with well‐organized low‐dimensional architectures provide significant thermodynamic and/or kinetic benefits for diverse applications. We present here the controlled synthesis of a novel class of hierarchical zirconium‐porphyrin frameworks ( ZrPHPs ) with nanosheet‐assembled hexagonal prism morphology. The crystal growth behaviors and structural evolution of ZrPHPs in an additive‐modulated solvothermal synthesis are examined, showing an “assembly‐hydrolysis‐reassembly” mechanism towards the formation of 2D nanosheets with ordered arrangement. Because of the highly‐accessible active sites harvesting broadband photons, ZrPHPs serve as adaptable photocatalysts to regulate macromolecular synthesis under full‐range visible light and natural sunlight. An initiator‐free, oxygen‐tolerant photopolymerization system is established, following a distinctive mechanism involving direct photo‐induced electron transfer to dormant species and hole‐mediated reversible deactivation. Specifically, ZrPHPs provide a surface‐confined effect towards the propagating chains which inhibits their recombination termination, enabling the highly‐efficient synthesis of ultrahigh molecular weight polymers ( M n >1,500,000) with relatively low dispersity ( Đ ≈1.5)." @default.
- W4386851059 created "2023-09-20" @default.
- W4386851059 creator A5003591630 @default.
- W4386851059 creator A5024049460 @default.
- W4386851059 creator A5032521963 @default.
- W4386851059 creator A5036145381 @default.
- W4386851059 creator A5046597133 @default.
- W4386851059 creator A5048379858 @default.
- W4386851059 creator A5050901470 @default.
- W4386851059 creator A5071776214 @default.
- W4386851059 creator A5077570500 @default.
- W4386851059 date "2023-10-02" @default.
- W4386851059 modified "2023-10-12" @default.
- W4386851059 title "Nanosheet‐Assembled Zirconium‐Porphyrin Frameworks Enabling Surface‐Confined, Initiator‐Free Photosynthesis of Ultrahigh Molecular Weight Polymers" @default.
- W4386851059 cites W1861100368 @default.
- W4386851059 cites W1971294738 @default.
- W4386851059 cites W1975588461 @default.
- W4386851059 cites W1979544533 @default.
- W4386851059 cites W1988762313 @default.
- W4386851059 cites W2007395042 @default.
- W4386851059 cites W2031430816 @default.
- W4386851059 cites W2058122340 @default.
- W4386851059 cites W2063941510 @default.
- W4386851059 cites W2083222334 @default.
- W4386851059 cites W2083930966 @default.
- W4386851059 cites W2084811043 @default.
- W4386851059 cites W2091071755 @default.
- W4386851059 cites W2118609172 @default.
- W4386851059 cites W2122427541 @default.
- W4386851059 cites W2155579681 @default.
- W4386851059 cites W2165206351 @default.
- W4386851059 cites W2340868187 @default.
- W4386851059 cites W2568118624 @default.
- W4386851059 cites W2597054437 @default.
- W4386851059 cites W2620242408 @default.
- W4386851059 cites W2784856116 @default.
- W4386851059 cites W2791476032 @default.
- W4386851059 cites W2792372796 @default.
- W4386851059 cites W2794303694 @default.
- W4386851059 cites W2801115881 @default.
- W4386851059 cites W2803069581 @default.
- W4386851059 cites W2805763782 @default.
- W4386851059 cites W2809835300 @default.
- W4386851059 cites W2811273000 @default.
- W4386851059 cites W2884495504 @default.
- W4386851059 cites W2886370720 @default.
- W4386851059 cites W2886665996 @default.
- W4386851059 cites W2891229549 @default.
- W4386851059 cites W2892002837 @default.
- W4386851059 cites W2915324629 @default.
- W4386851059 cites W2936033307 @default.
- W4386851059 cites W2985277657 @default.
- W4386851059 cites W3004318250 @default.
- W4386851059 cites W3009572686 @default.
- W4386851059 cites W3011683090 @default.
- W4386851059 cites W3011776714 @default.
- W4386851059 cites W3093224954 @default.
- W4386851059 cites W3094359911 @default.
- W4386851059 cites W3097805640 @default.
- W4386851059 cites W3099064763 @default.
- W4386851059 cites W3112636379 @default.
- W4386851059 cites W3203311505 @default.
- W4386851059 cites W4210545974 @default.
- W4386851059 cites W4284889425 @default.
- W4386851059 cites W4289515837 @default.
- W4386851059 doi "https://doi.org/10.1002/ange.202312697" @default.
- W4386851059 hasPublicationYear "2023" @default.
- W4386851059 type Work @default.
- W4386851059 citedByCount "0" @default.
- W4386851059 crossrefType "journal-article" @default.
- W4386851059 hasAuthorship W4386851059A5003591630 @default.
- W4386851059 hasAuthorship W4386851059A5024049460 @default.
- W4386851059 hasAuthorship W4386851059A5032521963 @default.
- W4386851059 hasAuthorship W4386851059A5036145381 @default.
- W4386851059 hasAuthorship W4386851059A5046597133 @default.
- W4386851059 hasAuthorship W4386851059A5048379858 @default.
- W4386851059 hasAuthorship W4386851059A5050901470 @default.
- W4386851059 hasAuthorship W4386851059A5071776214 @default.
- W4386851059 hasAuthorship W4386851059A5077570500 @default.
- W4386851059 hasConcept C127413603 @default.
- W4386851059 hasConcept C15487406 @default.
- W4386851059 hasConcept C159985019 @default.
- W4386851059 hasConcept C171250308 @default.
- W4386851059 hasConcept C185592680 @default.
- W4386851059 hasConcept C191897082 @default.
- W4386851059 hasConcept C192562407 @default.
- W4386851059 hasConcept C204389451 @default.
- W4386851059 hasConcept C2779480358 @default.
- W4386851059 hasConcept C42360764 @default.
- W4386851059 hasConcept C44228677 @default.
- W4386851059 hasConcept C51967427 @default.
- W4386851059 hasConcept C521977710 @default.
- W4386851059 hasConcept C534791751 @default.
- W4386851059 hasConcept C55493867 @default.
- W4386851059 hasConcept C75473681 @default.
- W4386851059 hasConceptScore W4386851059C127413603 @default.
- W4386851059 hasConceptScore W4386851059C15487406 @default.
- W4386851059 hasConceptScore W4386851059C159985019 @default.
- W4386851059 hasConceptScore W4386851059C171250308 @default.
- W4386851059 hasConceptScore W4386851059C185592680 @default.