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- W4386852857 abstract "We have fabricated a Ni (II)-Ru(II)-based heterometallo-supramolecular polymer (HMSMP)-modified glassy carbon electrode for the selective and sensitive electrochemical detection of sulfite (SO 3 2- ). The modified electrode (polyNiRu/GCE) was characterized by using scanning electron microscopy (SEM) and fourier transmission infrared (FT-IR) spectroscopy. Molecular weight of synthesized polymer (4.77 × 10 5 Da) was measured through intrinsic viscosity measurement following Mark-Houwink equation. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used to investigate the electrochemical behavior of the modified electrode. The modified electrode showed high sensitivity of 0.06 µAµM -1 cm -2 for SO 3 2- . The detection limit (S/N = 3) for SO 3 2- was 0.97 µM with a linear range of 10 to 1000 µM. The developed sensor was successfully examined for real sample analysis with tap water. Excellent recovery with lower relative standard deviation (RSD) and high stability for 4000s in analytic solution confirmed the reliability of using this polyNiRu/GCE in practical assessment." @default.
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- W4386852857 date "2023-08-28" @default.
- W4386852857 modified "2023-09-27" @default.
- W4386852857 title "Electrochemical Detection of Sulfite Using Ni-Ru-Based Heterometallo-Supramolecular Polymer" @default.
- W4386852857 doi "https://doi.org/10.1149/ma2023-01522615mtgabs" @default.
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