Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386853162> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W4386853162 endingPage "2576" @default.
- W4386853162 startingPage "2576" @default.
- W4386853162 abstract "Copper is a valuable material in renewable energy technologies, such as catalysts on gas diffusion electrodes in electrochemical devices for the electrochemical reduction of carbon dioxide (CO 2 ) to high-value products. By understanding the kinetics of ion-transfer in copper corrosion and deposition processes, we can gain a better understanding of the durability of devices that employ copper. Measurement of ion-transfer kinetics of bulk metal materials has a magnitude of challenges, increasing the difficulty of precisely analyzing the fundamentals of the processes. To assuage these concerns and obtain a more representative microscopic picture of Cu corrosion processes while investigating the effect of the anions on copper durability, we created several model microenvironments that employ copper underpotential deposition (UPD) on a well-ordered Au[111] surface: 1) a model system in sulfuric acid; 2) a bridging environment (methanesulfonic acid), and 3) a model microenvironment for gas diffusion (Nafion electrolyte). After analyzing these three systems, we expanded our models to investigate the effects of steric by adding ethanesulfonic acid and the effects of electronegativity by adding triflic acid. Our results demonstrate the effect of supporting anions on the ion-transfer kinetics of Cu UPD corrosion and deposition processes to give a better understanding of fundamental kinetics and mechanisms in gas diffusion environments. Figure 1" @default.
- W4386853162 created "2023-09-20" @default.
- W4386853162 creator A5003067415 @default.
- W4386853162 creator A5061632347 @default.
- W4386853162 creator A5067239128 @default.
- W4386853162 creator A5092900647 @default.
- W4386853162 date "2023-08-28" @default.
- W4386853162 modified "2023-09-27" @default.
- W4386853162 title "Model Systems for Understanding Ion-Transfer Kinetics in Corrosion" @default.
- W4386853162 doi "https://doi.org/10.1149/ma2023-01502576mtgabs" @default.
- W4386853162 hasPublicationYear "2023" @default.
- W4386853162 type Work @default.
- W4386853162 citedByCount "0" @default.
- W4386853162 crossrefType "journal-article" @default.
- W4386853162 hasAuthorship W4386853162A5003067415 @default.
- W4386853162 hasAuthorship W4386853162A5061632347 @default.
- W4386853162 hasAuthorship W4386853162A5067239128 @default.
- W4386853162 hasAuthorship W4386853162A5092900647 @default.
- W4386853162 hasConcept C121332964 @default.
- W4386853162 hasConcept C127413603 @default.
- W4386853162 hasConcept C144559425 @default.
- W4386853162 hasConcept C147789679 @default.
- W4386853162 hasConcept C148898269 @default.
- W4386853162 hasConcept C17525397 @default.
- W4386853162 hasConcept C177293861 @default.
- W4386853162 hasConcept C178790620 @default.
- W4386853162 hasConcept C179104552 @default.
- W4386853162 hasConcept C185592680 @default.
- W4386853162 hasConcept C192562407 @default.
- W4386853162 hasConcept C20625102 @default.
- W4386853162 hasConcept C2776572004 @default.
- W4386853162 hasConcept C2777869211 @default.
- W4386853162 hasConcept C2778199549 @default.
- W4386853162 hasConcept C42360764 @default.
- W4386853162 hasConcept C52859227 @default.
- W4386853162 hasConcept C544778455 @default.
- W4386853162 hasConcept C62520636 @default.
- W4386853162 hasConcept C68801617 @default.
- W4386853162 hasConcept C69357855 @default.
- W4386853162 hasConcept C97355855 @default.
- W4386853162 hasConceptScore W4386853162C121332964 @default.
- W4386853162 hasConceptScore W4386853162C127413603 @default.
- W4386853162 hasConceptScore W4386853162C144559425 @default.
- W4386853162 hasConceptScore W4386853162C147789679 @default.
- W4386853162 hasConceptScore W4386853162C148898269 @default.
- W4386853162 hasConceptScore W4386853162C17525397 @default.
- W4386853162 hasConceptScore W4386853162C177293861 @default.
- W4386853162 hasConceptScore W4386853162C178790620 @default.
- W4386853162 hasConceptScore W4386853162C179104552 @default.
- W4386853162 hasConceptScore W4386853162C185592680 @default.
- W4386853162 hasConceptScore W4386853162C192562407 @default.
- W4386853162 hasConceptScore W4386853162C20625102 @default.
- W4386853162 hasConceptScore W4386853162C2776572004 @default.
- W4386853162 hasConceptScore W4386853162C2777869211 @default.
- W4386853162 hasConceptScore W4386853162C2778199549 @default.
- W4386853162 hasConceptScore W4386853162C42360764 @default.
- W4386853162 hasConceptScore W4386853162C52859227 @default.
- W4386853162 hasConceptScore W4386853162C544778455 @default.
- W4386853162 hasConceptScore W4386853162C62520636 @default.
- W4386853162 hasConceptScore W4386853162C68801617 @default.
- W4386853162 hasConceptScore W4386853162C69357855 @default.
- W4386853162 hasConceptScore W4386853162C97355855 @default.
- W4386853162 hasIssue "50" @default.
- W4386853162 hasLocation W43868531621 @default.
- W4386853162 hasOpenAccess W4386853162 @default.
- W4386853162 hasPrimaryLocation W43868531621 @default.
- W4386853162 hasRelatedWork W2019068059 @default.
- W4386853162 hasRelatedWork W2037226231 @default.
- W4386853162 hasRelatedWork W2058664968 @default.
- W4386853162 hasRelatedWork W2068269495 @default.
- W4386853162 hasRelatedWork W2090614604 @default.
- W4386853162 hasRelatedWork W2379874956 @default.
- W4386853162 hasRelatedWork W2590062312 @default.
- W4386853162 hasRelatedWork W2906520900 @default.
- W4386853162 hasRelatedWork W3199407263 @default.
- W4386853162 hasRelatedWork W4249450781 @default.
- W4386853162 hasVolume "MA2023-01" @default.
- W4386853162 isParatext "false" @default.
- W4386853162 isRetracted "false" @default.
- W4386853162 workType "article" @default.