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- W4386854602 abstract "Polycyclic aromatic hydrocarbons (PAHs) containing fused pyrrole moieties are known as unique nitrogen-doped pi-conjugated molecules, e.g., azacoronenes, which possess a large π-conjugated planar structure and show rich redox properties. The related molecules are thus expected to be applied to redox-responsible optoelectronic materials. Furthermore, PAH-based compounds containing [4n]π-electron antiaromatic segments, such as pentalene and indacene are contributed to the ambipolar semiconducting material applications due to the distinct high HOMO and low LUMO energy levels. In this work, we have synthesized and characterized a novel N-doped poly-antiaromatic hydrocarbon (PAH) by the oxidative transformation of a dibenzocarbacorrole isomer, namely, dibenzocorrorin ( 1 ). X-ray crystal structure of the fused product ( 2 ) revealed a highly planar pi-conjugated structure containing a unique diaza-dicyclopentaazulene moiety. The distinct 12pi antiaromatic resonance structure led to the emergence of a near-infrared band beyond 1000 nm in the absorption spectrum and facile redox properties determined in the cyclic voltammetry. Furthermore, crystalline compound 2 showed carrier mobility in the single-crystal organic field effect transistor." @default.
- W4386854602 created "2023-09-20" @default.
- W4386854602 creator A5020129118 @default.
- W4386854602 date "2023-08-28" @default.
- W4386854602 modified "2023-09-27" @default.
- W4386854602 title "Synthesis and Properties of a Fused Antiaromatic Hydrocarbon By Oxidative Transformation of Carbacorrole Analogue" @default.
- W4386854602 doi "https://doi.org/10.1149/ma2023-01151416mtgabs" @default.
- W4386854602 hasPublicationYear "2023" @default.
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