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- W4386880035 abstract "Lignin is an important biomass resource to replace petrochemical industry for carbon neutrality. However, it is challenged by unyielding the trade-off between activity and selectivity owing to the chemical complexity and inherent heterogeneity of lignin biomacromolecule. Herein, we report that copper nanomaterial (CuO/C) derived from metal-organic framework (HKUST-1) could effectively catalytic hydrogenolysis of herbaceous plants into monomeric phenols (up to 29.5 wt%) through a lignin-first strategy, affording methyl 3-(4-hydroxyphenyl) propionate (1-H) and methyl 3-(4-hydroxy-3-methoxyphenyl) propionate (2-G) as the main monophenols with high selectivity of 31.9% and 17.3%. Moreover, we proposed two synthetic routes based on the purification and functionalization of those two compounds (1-H and 2-G) to synthesis 3-(4-carboxyphenyl) propionic acid and functional polyesters. Subsequent studies revealed that the temperature of 50% mass loss of the two polyesters reached 430–440 °C, indicating their robust thermal stability; while the DSC curves showed the difference between the two polymers in glass conversion temperature (Tg) and crystallization. In brief, this work opens a new avenue for the production of lignin-derived chemicals and materials." @default.
- W4386880035 created "2023-09-21" @default.
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- W4386880035 date "2023-11-01" @default.
- W4386880035 modified "2023-10-13" @default.
- W4386880035 title "Herbaceous lignin valorization through integrated copper-catalyzed hydrogenolysis and chemical functionalization" @default.
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- W4386880035 doi "https://doi.org/10.1016/j.compositesb.2023.111013" @default.
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