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- W4386893405 abstract "Four different Mn and Re catalysts for electrochemical CO2 reduction have been studied by IR spectroelectrochemistry (SEC) in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy= 4(4-aminophenyl)-2,2’-bipyridine) SEC suggests that a very slow catalytic reduction of CO2 occurs in acetonitrile also in the absence of proton donors, but at rather negative potentials. On the contrary, the corresponding Re(apbpy)(CO)3Br clearly displays a slow catalytic conversion already at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% of water as proton donor, the SEC of Mn(apbpy)(CO)3Br displays faster catalytic behavior." @default.
- W4386893405 created "2023-09-21" @default.
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- W4386893405 date "2023-09-19" @default.
- W4386893405 modified "2023-09-27" @default.
- W4386893405 title "New Spectroelectrochemical Insights in Mn and Re bipyridine Complexes as Catalysts for the Electrochemical Reduction of CO<sub>2</sub>" @default.
- W4386893405 doi "https://doi.org/10.20944/preprints202309.1169.v1" @default.
- W4386893405 hasPublicationYear "2023" @default.
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