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- W4386906108 abstract "A method was presented for the acylation of arenes using various aldehydes through dual CH activation at room temperature. The Pd-catalyst is initially activated to a triple state by absorbing energy from blue light. Furthermore, the 3Pd(AcO)2 required lower activation free energy to transition state 3(TS-2) based on the DFT calculation to ensure the reaction being proceeded at room temperature. This aldehyde-derived acyl radical merged with Pd-catalyzed activation of arenes to afford the cross coupling products." @default.
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- W4386906108 date "2023-11-01" @default.
- W4386906108 modified "2023-09-27" @default.
- W4386906108 title "The acylation with aldehydes via dual C-H activations by combining photocatalysis and palladium catalysis" @default.
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- W4386906108 doi "https://doi.org/10.1016/j.mcat.2023.113542" @default.
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