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- W4386914250 endingPage "111468" @default.
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- W4386914250 abstract "Unsymmetric bidentate ligands offer multiple binding modes with respect to the orientations of the coordinating sites, the unsymmetric nature of ligand 3,5-bis(3-pyridyl)-1,2,4-oxadiazole, L1 arises because of orientations of 3-pyridyl groups with respect to central 1,24-oxadiazole ring. Ligand L1 forms a discrete molecular octahedron [Pd6(L1)12](NO3)12, 1 when combined with Pd(NO3)2 in DMSO where the bound ligands are in cisoid-up orientation. In cage 1, Pd(II) ions are present at the vertices of the octahedron whereas twelve ligands are present at its edges, the opposite Pd-Pd distance in compound 1 is 17.501 Å. 1H NMR and DLS study of compound 1 with different guests reveals that resorcinol has interaction with the cage." @default.
- W4386914250 created "2023-09-22" @default.
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- W4386914250 date "2023-12-01" @default.
- W4386914250 modified "2023-09-30" @default.
- W4386914250 title "Coordination driven self-assembled 18-component molecular octahedron" @default.
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- W4386914250 doi "https://doi.org/10.1016/j.inoche.2023.111468" @default.
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