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- W4386914980 abstract "The main challenges in second near-infrared region molecular fluorophores are poor water solubility and unknown long-term toxicity at present. Herein, new NIR-II molecular fluorophores have been designed and employed to integrate biocompatible pillar[5]arene with 10 outer triethylene oxide groups for the synthesis of rotaxane IRCR. In addition, PEGylated pillar[5]arenes have been combined for the self-assembly of two supramolecular vesicular systems, i.e., PP5-IR1 and PP5-IR2, affording aqueous solubility and lowered cellular toxicity. In aqueous solution, all these fluorophores displayed room-temperature emission with λmax at 986–1013 nm and quantum yields of 0.54–1.45%. They also exhibited good chemical stability and reasonable self-assembled sizes, which may find potential applications in NIR-II imaging. In addition, PP5-IR1 can be used as a fluorescent chemosensor for selective recognition of glutathione through the cleavage of dinitrophenyl ether and release the fluorescent dye." @default.
- W4386914980 created "2023-09-22" @default.
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- W4386914980 date "2023-09-21" @default.
- W4386914980 modified "2023-10-17" @default.
- W4386914980 title "Synthesis, Optical Properties and Cellular Toxicity of Water-Soluble Near Infrared-II Fluorescent Assemblies Based on Pillar[5]arene" @default.
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- W4386914980 doi "https://doi.org/10.3390/polym15183853" @default.
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