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- W4386935846 endingPage "109128" @default.
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- W4386935846 abstract "Glycosyl radicals, produced under mild photoredox conditions, show unique utility in the preparation of C-linked glycoconjugates. We herein report the construction of C-glycosidic bonds on α,β-dehydroalanine (DHA) of peptides with easily available glycosyl bromides as glycosyl radical precursors under highly anomeric control, leading to C-glycosylation modifications of peptides. This method not only has outstanding functional group compatibility, but also is feasible in near-physiological conditions (pH ∼ 7 and temperature T ≤ 37°C in aqueous media)." @default.
- W4386935846 created "2023-09-22" @default.
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- W4386935846 date "2023-09-01" @default.
- W4386935846 modified "2023-10-16" @default.
- W4386935846 title "Photoredox-catalyzed C-glycosylation of peptides with glycosyl bromides" @default.
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- W4386935846 doi "https://doi.org/10.1016/j.cclet.2023.109128" @default.
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