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- W4386944173 abstract "We demonstrate here a synthetic strategy to prepare two distinct trimers of antiferromagnetically coupled {Cr7Ni} rings, substantially varying the magnetic interactions between the spin centres. The interactions were studied using multi-frequency cw EPR: in a trimer linked via non-covalent H-bonding interactions no measurable interaction between rings was seen, while in a trimer linked via iso-nicotinate groups isotropic and anisotropic exchange interactions of +0.42 and -0.8 GHz, respectively, were observed. The latter are the same as those for a simpler hetero-dimer system, showing how the spin-spin interactions can be built in a predictable and modular manner in these systems." @default.
- W4386944173 created "2023-09-23" @default.
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- W4386944173 date "2023-09-22" @default.
- W4386944173 modified "2023-09-28" @default.
- W4386944173 title "Control and transferability of magnetic interactions in supramolecular structures: trimers of {Cr7Ni} antiferromagnetic rings." @default.
- W4386944173 doi "https://doi.org/10.1002/chem.202302360" @default.
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- W4386944173 hasPublicationYear "2023" @default.
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