Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386945210> ?p ?o ?g. }
- W4386945210 abstract "Monofluoroalkene scaffolds are frequently found in various functional molecules. Herein, we report a Pd-IHept-catalyzed (NHC = N-heterocyclic carbene) defluorinative functionalization approach for the synthesis of monofluoroalkenes from gem-difluorocyclopropanes and malonates. The flexible yet sterically hindered N,N'-bis(2,6-di(4-heptyl)phenyl)imidazol-2-ylidene ligand plays a key role in ensuring the high reaction efficiency. In addition, sterically hindered 1,1- and 1,2-disubstituted gem-difluorocyclopropanes could also be used in this transformation." @default.
- W4386945210 created "2023-09-23" @default.
- W4386945210 creator A5018045286 @default.
- W4386945210 creator A5020469893 @default.
- W4386945210 creator A5030413037 @default.
- W4386945210 creator A5052111964 @default.
- W4386945210 date "2023-09-22" @default.
- W4386945210 modified "2023-09-28" @default.
- W4386945210 title "Pd-IHept-Catalyzed Ring-Opening of <i>gem</i>-Difluorocyclopropanes with Malonates Via Selective C–C Bond Cleavage: Synthesis of Monofluoroalkenes" @default.
- W4386945210 cites W1992996188 @default.
- W4386945210 cites W2001086298 @default.
- W4386945210 cites W2003555872 @default.
- W4386945210 cites W2005370295 @default.
- W4386945210 cites W2009008810 @default.
- W4386945210 cites W2011563365 @default.
- W4386945210 cites W2041914199 @default.
- W4386945210 cites W2057509100 @default.
- W4386945210 cites W2094065729 @default.
- W4386945210 cites W2095467227 @default.
- W4386945210 cites W2113861299 @default.
- W4386945210 cites W2116087305 @default.
- W4386945210 cites W2139232869 @default.
- W4386945210 cites W2169269629 @default.
- W4386945210 cites W2316492176 @default.
- W4386945210 cites W2318912282 @default.
- W4386945210 cites W2333129245 @default.
- W4386945210 cites W2335343215 @default.
- W4386945210 cites W2515502853 @default.
- W4386945210 cites W2701092419 @default.
- W4386945210 cites W2772621472 @default.
- W4386945210 cites W2784091834 @default.
- W4386945210 cites W2785609333 @default.
- W4386945210 cites W2795534721 @default.
- W4386945210 cites W2951419266 @default.
- W4386945210 cites W2956846774 @default.
- W4386945210 cites W2973544979 @default.
- W4386945210 cites W3002118643 @default.
- W4386945210 cites W3004788614 @default.
- W4386945210 cites W3090555831 @default.
- W4386945210 cites W3094725740 @default.
- W4386945210 cites W3115668446 @default.
- W4386945210 cites W3138243026 @default.
- W4386945210 cites W3153210831 @default.
- W4386945210 cites W3155134071 @default.
- W4386945210 cites W3163959912 @default.
- W4386945210 cites W3165676033 @default.
- W4386945210 cites W3176390173 @default.
- W4386945210 cites W3212052000 @default.
- W4386945210 cites W4220824848 @default.
- W4386945210 cites W4226245654 @default.
- W4386945210 cites W4244574878 @default.
- W4386945210 cites W4280624549 @default.
- W4386945210 cites W4281781938 @default.
- W4386945210 cites W4283656958 @default.
- W4386945210 cites W4284989448 @default.
- W4386945210 cites W4285494684 @default.
- W4386945210 cites W4288445873 @default.
- W4386945210 cites W4290805773 @default.
- W4386945210 cites W4291208076 @default.
- W4386945210 cites W4309243176 @default.
- W4386945210 cites W4311928501 @default.
- W4386945210 cites W4318954461 @default.
- W4386945210 cites W4362520602 @default.
- W4386945210 doi "https://doi.org/10.1021/acs.joc.3c00744" @default.
- W4386945210 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37737890" @default.
- W4386945210 hasPublicationYear "2023" @default.
- W4386945210 type Work @default.
- W4386945210 citedByCount "0" @default.
- W4386945210 crossrefType "journal-article" @default.
- W4386945210 hasAuthorship W4386945210A5018045286 @default.
- W4386945210 hasAuthorship W4386945210A5020469893 @default.
- W4386945210 hasAuthorship W4386945210A5030413037 @default.
- W4386945210 hasAuthorship W4386945210A5052111964 @default.
- W4386945210 hasConcept C115537861 @default.
- W4386945210 hasConcept C116569031 @default.
- W4386945210 hasConcept C127413603 @default.
- W4386945210 hasConcept C147789679 @default.
- W4386945210 hasConcept C155647269 @default.
- W4386945210 hasConcept C161790260 @default.
- W4386945210 hasConcept C170493617 @default.
- W4386945210 hasConcept C175156509 @default.
- W4386945210 hasConcept C178790620 @default.
- W4386945210 hasConcept C185592680 @default.
- W4386945210 hasConcept C187320778 @default.
- W4386945210 hasConcept C201194858 @default.
- W4386945210 hasConcept C21951064 @default.
- W4386945210 hasConcept C2777164566 @default.
- W4386945210 hasConcept C2780378348 @default.
- W4386945210 hasConcept C3044715 @default.
- W4386945210 hasConcept C32909587 @default.
- W4386945210 hasConcept C43369102 @default.
- W4386945210 hasConcept C55493867 @default.
- W4386945210 hasConcept C71240020 @default.
- W4386945210 hasConceptScore W4386945210C115537861 @default.
- W4386945210 hasConceptScore W4386945210C116569031 @default.
- W4386945210 hasConceptScore W4386945210C127413603 @default.
- W4386945210 hasConceptScore W4386945210C147789679 @default.
- W4386945210 hasConceptScore W4386945210C155647269 @default.
- W4386945210 hasConceptScore W4386945210C161790260 @default.
- W4386945210 hasConceptScore W4386945210C170493617 @default.