FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386945492> ?p ?o ?g. }

• W4386945492 endingPage "21611" @default.
• W4386945492 startingPage "21600" @default.
• W4386945492 abstract "Silicon (Si)-based anodes are currently considered a feasible solution to improve the energy density of lithium-ion batteries owing to their sufficient specific capacity and natural abundance. However, Si-based anodes exhibit low electric conductivities and large volume changes during cycling, which could easily trigger continuous breakdown/reparation of the as-formed solid-electrolyte-interphase (SEI) layer, seriously hampering their practical application in current battery technology. To control the chemoelectrochemical instability of the conventional SEI layer, we herein propose the introduction of elemental sulfur into nonaqueous electrolytes, aiming to build a sulfur-mediated gradient interphase (SMGI) layer on Si-based anodes. The SMGI layer is generated through the domino reactions (i.e., electrochemical cascade reactions) involving the electrochemical reductions of elemental sulfur followed by nucleophilic substitutions of fluoroethylene carbonate, which endows the corresponding SEI layer with strong elasticity and chemomechanical stability and enables rapid transportation of Li+ ions. Consequently, the prototype Si||LiNi0.8Co0.1Mn0.1O2 cells attain a high-energy density of 622.2 W h kg–1 and a capacity retention of 88.8% after 100 cycles. Unlike previous attempts based on sophisticated chemical modifications of electrolyte components, this study opens a new avenue in interphase design for long-lived and high-energy rechargeable batteries." @default.
• W4386945492 created "2023-09-23" @default.
• W4386945492 creator A5007192276 @default.
• W4386945492 creator A5008374553 @default.
• W4386945492 creator A5009493932 @default.
• W4386945492 creator A5024406536 @default.
• W4386945492 creator A5032677667 @default.
• W4386945492 creator A5037337015 @default.
• W4386945492 creator A5046851457 @default.
• W4386945492 creator A5047955654 @default.
• W4386945492 creator A5052815761 @default.
• W4386945492 creator A5055227491 @default.
• W4386945492 creator A5074307226 @default.
• W4386945492 date "2023-09-22" @default.
• W4386945492 modified "2023-10-16" @default.
• W4386945492 title "Domino Reactions Enabling Sulfur-Mediated Gradient Interphases for High-Energy Lithium Batteries" @default.
• W4386945492 cites W1977828436 @default.
• W4386945492 cites W2006318126 @default.
• W4386945492 cites W2051699520 @default.
• W4386945492 cites W2062517395 @default.
• W4386945492 cites W2093989441 @default.
• W4386945492 cites W2113095835 @default.
• W4386945492 cites W2151207643 @default.
• W4386945492 cites W2169211003 @default.
• W4386945492 cites W2322892597 @default.
• W4386945492 cites W2331458798 @default.
• W4386945492 cites W2340971382 @default.
• W4386945492 cites W2510588512 @default.
• W4386945492 cites W2522472223 @default.
• W4386945492 cites W2751157745 @default.
• W4386945492 cites W2787430363 @default.
• W4386945492 cites W2810866966 @default.
• W4386945492 cites W2908934295 @default.
• W4386945492 cites W2946604523 @default.
• W4386945492 cites W2976289009 @default.
• W4386945492 cites W2983762108 @default.
• W4386945492 cites W3016996355 @default.
• W4386945492 cites W3126399067 @default.
• W4386945492 cites W3131561762 @default.
• W4386945492 cites W3134159373 @default.
• W4386945492 cites W3134932327 @default.
• W4386945492 cites W3149089545 @default.
• W4386945492 cites W3155386667 @default.
• W4386945492 cites W3184391242 @default.
• W4386945492 cites W3191719568 @default.
• W4386945492 cites W3195101858 @default.
• W4386945492 cites W3201212194 @default.
• W4386945492 cites W3217552657 @default.
• W4386945492 cites W4206988986 @default.
• W4386945492 cites W4210482835 @default.
• W4386945492 cites W4212930590 @default.
• W4386945492 cites W4226026517 @default.
• W4386945492 cites W4229057301 @default.
• W4386945492 cites W4280587604 @default.
• W4386945492 cites W4286005561 @default.
• W4386945492 cites W4286771091 @default.
• W4386945492 cites W4290851984 @default.
• W4386945492 cites W4290960456 @default.
• W4386945492 cites W4292857641 @default.
• W4386945492 cites W4293193462 @default.
• W4386945492 cites W4293373946 @default.
• W4386945492 cites W4304698197 @default.
• W4386945492 cites W4307580630 @default.
• W4386945492 cites W4308025474 @default.
• W4386945492 cites W4310573114 @default.
• W4386945492 cites W4313499676 @default.
• W4386945492 cites W4315784558 @default.
• W4386945492 cites W4380363414 @default.
• W4386945492 doi "https://doi.org/10.1021/jacs.3c07908" @default.
• W4386945492 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37737723" @default.
• W4386945492 hasPublicationYear "2023" @default.
• W4386945492 type Work @default.
• W4386945492 citedByCount "0" @default.
• W4386945492 crossrefType "journal-article" @default.
• W4386945492 hasAuthorship W4386945492A5007192276 @default.
• W4386945492 hasAuthorship W4386945492A5008374553 @default.
• W4386945492 hasAuthorship W4386945492A5009493932 @default.
• W4386945492 hasAuthorship W4386945492A5024406536 @default.
• W4386945492 hasAuthorship W4386945492A5032677667 @default.
• W4386945492 hasAuthorship W4386945492A5037337015 @default.
• W4386945492 hasAuthorship W4386945492A5046851457 @default.
• W4386945492 hasAuthorship W4386945492A5047955654 @default.
• W4386945492 hasAuthorship W4386945492A5052815761 @default.
• W4386945492 hasAuthorship W4386945492A5055227491 @default.
• W4386945492 hasAuthorship W4386945492A5074307226 @default.
• W4386945492 hasConcept C127413603 @default.
• W4386945492 hasConcept C134018914 @default.
• W4386945492 hasConcept C147789679 @default.
• W4386945492 hasConcept C17525397 @default.
• W4386945492 hasConcept C178790620 @default.
• W4386945492 hasConcept C179104552 @default.
• W4386945492 hasConcept C185592680 @default.
• W4386945492 hasConcept C2778541603 @default.
• W4386945492 hasConcept C29452124 @default.
• W4386945492 hasConcept C42360764 @default.
• W4386945492 hasConcept C518881349 @default.
• W4386945492 hasConcept C52859227 @default.
• W4386945492 hasConcept C54355233 @default.

• next