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- W4386947089 abstract "Precise charge transfer modification and efficient activation of peroxymonosulfate are effective methods for increasing photocatalytic efficiency. Here, BiOBr/MnCo2O4 photocatalysts with abundant Mn-Br bonds were generated by immobilizing the exposed {110} facets of BiOBr in the marigold-like MnCo2O4. The prepared BiOBr/MnCo2O4 retained the marigold-like morphology of MnCo2O4 while exhibiting good adsorption properties and interface contact effects. More importantly, the interfacial Mn-Br bond between MnCo2O4 and BiOBr functioned as charge transport bridges, allowing for a directional transfer channel and lowering the potential energy barrier for interfacial charge transfer. In addition, the exposure of the {110} facets exhibited more Mn atom-anchored sites for easy anchoring of BiOBr, significantly solving the stability problem of the bismuth material. Compared to MnCo2O4 + BiOBr, which did not form Mn-Br bonds, the MnCo2O4/BiOBr heterojunction had more efficient photocatalytic activity (1.3 times) and stability. This suggested that using electronic bridges for directional charge transfer was an efficient way to improve photocatalytic efficiency." @default.
- W4386947089 created "2023-09-23" @default.
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- W4386947089 date "2024-01-01" @default.
- W4386947089 modified "2023-09-30" @default.
- W4386947089 title "Exposed {1 1 0} facets of BiOBr anchored to marigold-like MnCo2O4 with abundant interfacial electron transfer bridges and efficient activation of peroxymonosulfate" @default.
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- W4386947089 doi "https://doi.org/10.1016/j.jcis.2023.09.106" @default.
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