Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386951471> ?p ?o ?g. }
- W4386951471 endingPage "136699" @default.
- W4386951471 startingPage "136699" @default.
- W4386951471 abstract "The 2-benzoylpyridine-semicarbazone and 2-benzoylpyridine-N-4-phenylsemicarbazone can be prepared in their hydrochloride forms, having good solubility in water and/or methanol. We have used these compounds, named [H2L]Cl] and [H2LPh]Cl, as pre-ligands in reactions with SnCl2·2H2O in pure water or water/methanol mixtures. Four SnII coordination compounds were obtained and structurally analyzed by single-crystal X-ray diffraction: [Sn(HL)Cl][SnCl3] (1), [Sn(HL)(NCS)2] (2), [Sn(HLPh)Cl2] (3) and [Sn(HLPh)(NCS)2] (4). The 5s2 electron pair of SnII produced a clear gap in all compounds, which was fulfilled by tetrel bonds. The Sn‒Cl or Sn‒S tetrel bonds generated the pseudo-polymeric structures of 1 and 2, and the pseudo-dimeric structures of 3 and 4. Hydrogen bonds arranged the pseudo-polymers and pseudo-dimers into two-dimensional nets. Spectroscopic techniques, thermogravimetric analysis, and powder X-ray diffraction complemented the characterization of the compounds. Polymorphism was found for 3. Antimicrobial activity against bacterial and mycobacterial strains was evaluated. MIC values of 0.0976‒3.125 mM against M. abscessus, M. massiliense and M. fortuitum were obtained for compounds 1‒4." @default.
- W4386951471 created "2023-09-23" @default.
- W4386951471 creator A5025440647 @default.
- W4386951471 creator A5044230916 @default.
- W4386951471 creator A5050171121 @default.
- W4386951471 creator A5065624902 @default.
- W4386951471 creator A5065921949 @default.
- W4386951471 creator A5080529887 @default.
- W4386951471 creator A5092921011 @default.
- W4386951471 date "2024-01-01" @default.
- W4386951471 modified "2023-10-18" @default.
- W4386951471 title "Easy obtention of tin(II) complexes by using semicarbazones in their hydrochloride forms" @default.
- W4386951471 cites W1486288260 @default.
- W4386951471 cites W1982170797 @default.
- W4386951471 cites W1988232871 @default.
- W4386951471 cites W1993170415 @default.
- W4386951471 cites W2016373164 @default.
- W4386951471 cites W2020309776 @default.
- W4386951471 cites W2021268666 @default.
- W4386951471 cites W2038288584 @default.
- W4386951471 cites W2048747442 @default.
- W4386951471 cites W2054292762 @default.
- W4386951471 cites W2061733551 @default.
- W4386951471 cites W2063881867 @default.
- W4386951471 cites W2064026067 @default.
- W4386951471 cites W2066151517 @default.
- W4386951471 cites W2069139836 @default.
- W4386951471 cites W2076079544 @default.
- W4386951471 cites W2079851525 @default.
- W4386951471 cites W2083347665 @default.
- W4386951471 cites W2091965993 @default.
- W4386951471 cites W2124041730 @default.
- W4386951471 cites W2139064648 @default.
- W4386951471 cites W2144048071 @default.
- W4386951471 cites W2154002154 @default.
- W4386951471 cites W2159327408 @default.
- W4386951471 cites W2330410004 @default.
- W4386951471 cites W2489692237 @default.
- W4386951471 cites W2553249585 @default.
- W4386951471 cites W2591969358 @default.
- W4386951471 cites W2625433191 @default.
- W4386951471 cites W2787477033 @default.
- W4386951471 cites W2792143027 @default.
- W4386951471 cites W2794135597 @default.
- W4386951471 cites W2901877187 @default.
- W4386951471 cites W2914450201 @default.
- W4386951471 cites W2943279811 @default.
- W4386951471 cites W2961164135 @default.
- W4386951471 cites W2979197195 @default.
- W4386951471 cites W3046968067 @default.
- W4386951471 cites W3183347883 @default.
- W4386951471 cites W4200362657 @default.
- W4386951471 cites W4293069346 @default.
- W4386951471 cites W4385355353 @default.
- W4386951471 cites W78337159 @default.
- W4386951471 doi "https://doi.org/10.1016/j.molstruc.2023.136699" @default.
- W4386951471 hasPublicationYear "2024" @default.
- W4386951471 type Work @default.
- W4386951471 citedByCount "0" @default.
- W4386951471 crossrefType "journal-article" @default.
- W4386951471 hasAuthorship W4386951471A5025440647 @default.
- W4386951471 hasAuthorship W4386951471A5044230916 @default.
- W4386951471 hasAuthorship W4386951471A5050171121 @default.
- W4386951471 hasAuthorship W4386951471A5065624902 @default.
- W4386951471 hasAuthorship W4386951471A5065921949 @default.
- W4386951471 hasAuthorship W4386951471A5080529887 @default.
- W4386951471 hasAuthorship W4386951471A5092921011 @default.
- W4386951471 hasConcept C112887158 @default.
- W4386951471 hasConcept C115624301 @default.
- W4386951471 hasConcept C178790620 @default.
- W4386951471 hasConcept C185592680 @default.
- W4386951471 hasConcept C2776460385 @default.
- W4386951471 hasConcept C2779607525 @default.
- W4386951471 hasConcept C32909587 @default.
- W4386951471 hasConcept C525849907 @default.
- W4386951471 hasConcept C60100273 @default.
- W4386951471 hasConcept C71240020 @default.
- W4386951471 hasConcept C8010536 @default.
- W4386951471 hasConcept C83591994 @default.
- W4386951471 hasConceptScore W4386951471C112887158 @default.
- W4386951471 hasConceptScore W4386951471C115624301 @default.
- W4386951471 hasConceptScore W4386951471C178790620 @default.
- W4386951471 hasConceptScore W4386951471C185592680 @default.
- W4386951471 hasConceptScore W4386951471C2776460385 @default.
- W4386951471 hasConceptScore W4386951471C2779607525 @default.
- W4386951471 hasConceptScore W4386951471C32909587 @default.
- W4386951471 hasConceptScore W4386951471C525849907 @default.
- W4386951471 hasConceptScore W4386951471C60100273 @default.
- W4386951471 hasConceptScore W4386951471C71240020 @default.
- W4386951471 hasConceptScore W4386951471C8010536 @default.
- W4386951471 hasConceptScore W4386951471C83591994 @default.
- W4386951471 hasFunder F4320321091 @default.
- W4386951471 hasFunder F4320322904 @default.
- W4386951471 hasLocation W43869514711 @default.
- W4386951471 hasOpenAccess W4386951471 @default.
- W4386951471 hasPrimaryLocation W43869514711 @default.
- W4386951471 hasRelatedWork W1765072828 @default.
- W4386951471 hasRelatedWork W2025276268 @default.