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- W4386959748 abstract "Single-walled carbon nanotubes (SWCNTs) are characteristic one-dimensional nanomaterials, with length as their defining feature. However, the exploration of length-dependent properties in semiconducting-SWCNTs (s-SWCNTs) has hitherto been underexplored, primarily due to the absence of precise preparation technologies to obtain s-SWCNTs with both controlled length and narrow length distribution. Here, we introduced a novel approach based on electrochemical shortening and selective adsorption, offering control over the SWCNTs' length and their distributions. This methodology is compatible with high-purity SWCNTs sorting techniques. We have conducted detailed length statistics and comparisons of the truncation results of SWCNTs with different diameters. Experimental results demonstrate that smaller-diameter SWCNTs s are more prone to truncation, resulting in shorter lengths. Remarkably, we observed a length-dependent fluorescence enhancement when the length of s-SWCNTs was reduced to less than 120 nm, akin to the behavior of carbon dots or conjugated polymers. This research paves the way for exploring more length-dependent properties and length-related applications of s-SWCNTs." @default.
- W4386959748 created "2023-09-23" @default.
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- W4386959748 date "2023-11-01" @default.
- W4386959748 modified "2023-09-29" @default.
- W4386959748 title "Length-controlled sorting and length-dependent properties of short semiconducting single-walled carbon nanotubes" @default.
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- W4386959748 doi "https://doi.org/10.1016/j.carbon.2023.118468" @default.
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