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• W4386960136 endingPage "1665" @default.
• W4386960136 startingPage "1665" @default.
• W4386960136 abstract "This study investigated the impact of adding zinc oxide nanoparticles (ZnO-NPs) to electrospun membranes and cast films made of poly(ε-caprolactone) (PCL). The physicochemical, mechanical, and morphological properties of the samples were analyzed. Physicochemical parameters included water contact angle (WCA), water vapor transmission rate (WVTR), permeance, water vapor permeability (WVP), light transmission (T600), and transparency (T). Mechanical properties, such as maximum stress (Ϭmax), elongation (εmax), and Young’s modulus (MPa), were also evaluated. Morphological properties were analyzed in terms of thickness, dispersion, and surface roughness (measured by the arithmetic (Ra) and quadratic (Rq) averages). The crystallinity and melting point, as well as the functional DPPH• scavenging percentage (SP%), were also studied. The results showed that adding 1 wt% ZnO-NPs improved the water barrier properties of PCL membranes and films, increasing WCA by 1%–6% and decreasing WVTR by 11%–19%, permeance by 34%–20%, and WVP by 4%–11%, respectively. The T600 values of PCL/ZnO-NPs membranes and films were 2–3 times lower than those of neat PCL samples, indicating improved optical properties. The mechanical properties of the composite membranes and films also improved, with Ϭmax increasing by 56%–32% and Young’s modulus increasing by 91%–95%, while εmax decreased by 79%–57%. The incorporation of ZnO-NPs also increased the thickness and surface roughness of the samples. The SP% of PCL/ZnO-NPs increased by almost 69%, demonstrating the beneficial effects of ZnO-NPs on the system. These findings suggest that incorporating ZnO-NPs into PCL membranes and films can enhance their properties, making them well suited for various applications, such as those within the realm of materials science and nanotechnology." @default.
• W4386960136 created "2023-09-23" @default.
• W4386960136 creator A5003110581 @default.
• W4386960136 creator A5003354694 @default.
• W4386960136 creator A5009869341 @default.
• W4386960136 creator A5046821940 @default.
• W4386960136 date "2023-09-22" @default.
• W4386960136 modified "2023-10-03" @default.
• W4386960136 title "Sustainable Integration of Zinc Oxide Nanoparticles: Enhancing Properties of Poly(ε-Caprolactone) Electrospun Nanofibers and Cast Films" @default.
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