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- W4386964170 abstract "A simple and efficient protocol for the synthesis of arylmethyl substituted organophosphorus compounds is presented. This method involves the reaction of diphenyl phosphite with aldehydes in the presence of BF3-Et2O. In this method, BF3-Et2O plays a dual role, as it facilitates the generation of both hydrophosphonylated intermediate and phenol from diphenyl phosphite. A significant feature of this approach is its tolerance to the presence of external nucleophiles, such as phenol, aliphatic thiols, indole and 3-methylanisole. The simplicity of the reaction conditions and the high yields achieved make this method promising for applications in areas where phosphonate compounds are of interest." @default.
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- W4386964170 date "2023-01-01" @default.
- W4386964170 modified "2023-10-13" @default.
- W4386964170 title "BF3-Et2O Promoted Bifunctionalization of Aldehydes for the Synthesis of Arylmethyl Substituted Organophosphorus Compounds" @default.
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- W4386964170 doi "https://doi.org/10.1039/d3cc03898j" @default.
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