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• W4386967803 abstract "Rationale Improving the analytical performance of linear ion traps (LITs) is crucial for the advancement of high‐performance LIT mass spectrometers. In this study, a double resonant excitation method was employed in an asymmetric LIT to achieve high ion unidirectional ejection efficiency and enhanced mass resolution. Methods The asymmetric trapping field was generated by stretching one x electrode with a distance α . The double resonant excitation was achieved by applying an alternating voltage out of phase and a supplementary alternating voltage in phase to the x and y electrode pairs of the LIT, respectively. Numerical simulations of ion trajectories were performed to validate the effectiveness of this method. Results The mass resolution of the asymmetric LIT with double resonant excitation could be improved to ~3800, which was over two times compared to that with only dipolar resonant excitation, while both reached ~90% in ion unidirectional ejection efficiency. Conclusions By employing the double resonant excitation method, the mass resolution could be improved significantly in the asymmetric LIT, while maintaining a considerably high ion unidirectional ejection efficiency. This method might provide a general solution for enhancing ion detection efficiency and mass resolution of LIT mass spectrometers." @default.
• W4386967803 created "2023-09-23" @default.
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• W4386967803 date "2023-09-22" @default.
• W4386967803 modified "2023-10-17" @default.
• W4386967803 title "Simulation of double resonant excitation of ions in an asymmetric linear ion trap mass analyzer" @default.
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• W4386967803 doi "https://doi.org/10.1002/rcm.9625" @default.
• W4386967803 hasPublicationYear "2023" @default.
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