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- W4386989147 abstract "A new family of copolymers based on styrene and a polymerizable cinchonidine thioamide derivative was synthesized by conventional radical polymerization. The copolymers were tested as homogeneous supported organocatalysts in the enantioselective decarboxylative protonation (EDP) of α-aminomalonate hemiesters giving access to α-amino acids under very mild conditions. These macromolecular catalysts could be prepared on a large scale and outperformed their unsupported analogues providing the desired products in high yield and enantioselectivity. Furthermore, recycling experiments were conducted which showed good enantioselectivities." @default.
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- W4386989147 date "2023-11-01" @default.
- W4386989147 modified "2023-09-30" @default.
- W4386989147 title "Polymer-supported thioamide-derived cinchona alkaloids as efficient organocatalysts for the enantioselective decarboxylative protonation" @default.
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- W4386989147 doi "https://doi.org/10.1016/j.reactfunctpolym.2023.105731" @default.
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