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- W4386996294 endingPage "6381" @default.
- W4386996294 startingPage "6381" @default.
- W4386996294 abstract "Two-dimensional (2D) materials and phenomena attract huge attention in modern science. Herein, we introduce a family of layered materials inspired by the minerals valleriite and tochilinite, which are composed of alternating incompatible, and often incommensurate, quasi-atomic sheets of transition metal chalcogenide (sulfides and selenides of Fe, Fe-Cu and other metals) and hydroxide of Mg, Al, Fe, Li, etc., stacked via electrostatic interaction rather than van der Waals forces. We survey the data available on the composition and structure of the layered minerals, laboratory syntheses of such materials and the effect of reaction conditions on the phase purity, morphology and composition of the products. The spectroscopic results (Mössbauer, X-ray photoelectron, X-ray absorption, Raman, UV-vis, etc.), physical (electron, magnetic, optical and some others) characteristics, a specificity of thermal behavior of the materials are discussed. The family of superconductors (FeSe)·(Li,Fe)(OH) having a similar layered structure is briefly considered too. Finally, promising research directions and applications of the valleriite-type substances as a new class of prospective multifunctional 2D materials are outlined." @default.
- W4386996294 created "2023-09-25" @default.
- W4386996294 creator A5002957454 @default.
- W4386996294 creator A5012127467 @default.
- W4386996294 creator A5029209859 @default.
- W4386996294 creator A5048646370 @default.
- W4386996294 creator A5091595419 @default.
- W4386996294 date "2023-09-24" @default.
- W4386996294 modified "2023-10-18" @default.
- W4386996294 title "Metal Chalcogenide–Hydroxide Hybrids as an Emerging Family of Two-Dimensional Heterolayered Materials: An Early Review" @default.
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