FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387005024> ?p ?o ?g. }

• W4387005024 endingPage "123338" @default.
• W4387005024 startingPage "123338" @default.
• W4387005024 abstract "Metal-free catalysts without metal active sites participating in the reactions have obtained growing attraction under the drive of the economic and environmental problems. Here, 2D-COFs-drived B/N co-doped carbon nanosheets as metal-free catalyst was synthesized by Schiff-based coupling reaction and self-templated carbonization. It shows excellent catalytic performance in nitro compound hydrogenation reaction as all-solid FLP catalyst in H2 system (100% conversion of nitrobenzene and 99.89% selectivity to aniline) without any metal active species in the catalyst. This result is the most promising compared to the previous literatures. In the study, the high crystallinity of precursor 2D-COFs is imperative for catalytic stability, and the function of B atoms modification and the B-N synergism were investigated carefully. The formation of B-N bond as a fixed all-solid FLP active center was verified, and it also indicates that B atoms introduction can make the carbon nanosheets orderly and enhance the strength and amount of the acid and base sites. The catalytic mechanism of hydrogen activation was also studied by combining the characterization results and density functional theory (DFT) calculations. The results show that the B atoms doping and defects formation efficiently accelerate the charges aggregation between B-N bonds to form Lewis pairs, and the TS searching calculations shows the significant decrease of H2 dissociation barrier energy and the reaction energy, demonstrating the effectiveness of N and B co-doping strategy. This work is very promising and the metal-free catalyst is the potential alternative to traditional metal catalysts." @default.
• W4387005024 created "2023-09-26" @default.
• W4387005024 creator A5013395601 @default.
• W4387005024 creator A5036346400 @default.
• W4387005024 creator A5050188864 @default.
• W4387005024 creator A5067048710 @default.
• W4387005024 creator A5073575140 @default.
• W4387005024 date "2024-02-01" @default.
• W4387005024 modified "2023-10-08" @default.
• W4387005024 title "2D-COFs-derived Heteroatom-doped Carbon Nanosheets as High-efficiency All-solid Frustrated Lewis Pair Metal-free Hydrogenation Catalyst" @default.
• W4387005024 cites W1973617631 @default.
• W4387005024 cites W1979386110 @default.
• W4387005024 cites W1980373999 @default.
• W4387005024 cites W2017531559 @default.
• W4387005024 cites W2078119700 @default.
• W4387005024 cites W2115786060 @default.
• W4387005024 cites W2143224885 @default.
• W4387005024 cites W2292770293 @default.
• W4387005024 cites W2310352422 @default.
• W4387005024 cites W2318977385 @default.
• W4387005024 cites W2462698922 @default.
• W4387005024 cites W2561849115 @default.
• W4387005024 cites W2593311223 @default.
• W4387005024 cites W2621338197 @default.
• W4387005024 cites W2732587168 @default.
• W4387005024 cites W2767896876 @default.
• W4387005024 cites W2773091193 @default.
• W4387005024 cites W2774945140 @default.
• W4387005024 cites W2788398387 @default.
• W4387005024 cites W2794979826 @default.
• W4387005024 cites W2807400202 @default.
• W4387005024 cites W2895944291 @default.
• W4387005024 cites W2945553028 @default.
• W4387005024 cites W2969687397 @default.
• W4387005024 cites W2994170971 @default.
• W4387005024 cites W3004327229 @default.
• W4387005024 cites W3014695970 @default.
• W4387005024 cites W3027112317 @default.
• W4387005024 cites W3029623368 @default.
• W4387005024 cites W3097586682 @default.
• W4387005024 cites W3106642332 @default.
• W4387005024 cites W3112912837 @default.
• W4387005024 cites W3116230488 @default.
• W4387005024 cites W3135681556 @default.
• W4387005024 cites W3185542652 @default.
• W4387005024 cites W3194628252 @default.
• W4387005024 cites W3199949357 @default.
• W4387005024 cites W3203920515 @default.
• W4387005024 cites W4206938234 @default.
• W4387005024 cites W4224050442 @default.
• W4387005024 cites W4244922305 @default.
• W4387005024 cites W4280630160 @default.
• W4387005024 cites W4283388073 @default.
• W4387005024 cites W4283830418 @default.
• W4387005024 cites W4297176396 @default.
• W4387005024 cites W4302774397 @default.
• W4387005024 cites W4306406146 @default.
• W4387005024 cites W4313649683 @default.
• W4387005024 cites W4320476292 @default.
• W4387005024 cites W4320487433 @default.
• W4387005024 doi "https://doi.org/10.1016/j.apcatb.2023.123338" @default.
• W4387005024 hasPublicationYear "2024" @default.
• W4387005024 type Work @default.
• W4387005024 citedByCount "0" @default.
• W4387005024 crossrefType "journal-article" @default.
• W4387005024 hasAuthorship W4387005024A5013395601 @default.
• W4387005024 hasAuthorship W4387005024A5036346400 @default.
• W4387005024 hasAuthorship W4387005024A5050188864 @default.
• W4387005024 hasAuthorship W4387005024A5067048710 @default.
• W4387005024 hasAuthorship W4387005024A5073575140 @default.
• W4387005024 hasConcept C127413603 @default.
• W4387005024 hasConcept C147597530 @default.
• W4387005024 hasConcept C150394285 @default.
• W4387005024 hasConcept C152365726 @default.
• W4387005024 hasConcept C154877778 @default.
• W4387005024 hasConcept C161790260 @default.
• W4387005024 hasConcept C163638829 @default.
• W4387005024 hasConcept C178790620 @default.
• W4387005024 hasConcept C185592680 @default.
• W4387005024 hasConcept C192562407 @default.
• W4387005024 hasConcept C20950531 @default.
• W4387005024 hasConcept C2780263894 @default.
• W4387005024 hasConcept C39679061 @default.
• W4387005024 hasConcept C42360764 @default.
• W4387005024 hasConcept C544153396 @default.
• W4387005024 hasConceptScore W4387005024C127413603 @default.
• W4387005024 hasConceptScore W4387005024C147597530 @default.
• W4387005024 hasConceptScore W4387005024C150394285 @default.
• W4387005024 hasConceptScore W4387005024C152365726 @default.
• W4387005024 hasConceptScore W4387005024C154877778 @default.
• W4387005024 hasConceptScore W4387005024C161790260 @default.
• W4387005024 hasConceptScore W4387005024C163638829 @default.
• W4387005024 hasConceptScore W4387005024C178790620 @default.
• W4387005024 hasConceptScore W4387005024C185592680 @default.
• W4387005024 hasConceptScore W4387005024C192562407 @default.
• W4387005024 hasConceptScore W4387005024C20950531 @default.
• W4387005024 hasConceptScore W4387005024C2780263894 @default.
• W4387005024 hasConceptScore W4387005024C39679061 @default.

• next