FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387008013> ?p ?o ?g. }

• W4387008013 endingPage "121421" @default.
• W4387008013 startingPage "121421" @default.
• W4387008013 abstract "Galactomannan stands as a promising heteropolysaccharide, yet its randomly distributed non-linear structures and high molecular mass remain a huge challenge in solubilization and wide range of chemical modifications. This work develops a task specific approach for efficient dissolve of galactomannan in ionic liquids (ILs) by destructing and reconstructing intermolecular/intramolecular hydrogen bonds of galactomannan. Combining density functional theory calculations and experimental results, a reasonable mechanism of polysaccharide dissolution is proposed that the hydrogen bond networks of polysaccharide are broken, thus the hydroxyl groups are fully exposed and activated to facilitate functionalization. In view of the enhanced solubilization, an excellent effect in selenylation of galactomannan is notably improved by employing ILs with dual roles as solvents and catalysts. Typically, the introduction of -SO3H in ILs (SFILs) effectively enhances the protonation ability of selenium donor and thus further improves the functionalization efficiency. Furthermore, a surprising finding is observed that selenium content and average molecular mass of functionalized polysaccharide can be manipulated by the anions-cations synergistic effect which is highly dependent on SFILs acidity strength. This work proposed an integrated and promising strategy for improving the solubilization and functionalization manipulating by ILs, showing a great referential value for the widespread application in polysaccharide-rich resources." @default.
• W4387008013 created "2023-09-26" @default.
• W4387008013 creator A5004082387 @default.
• W4387008013 creator A5007613197 @default.
• W4387008013 creator A5008600174 @default.
• W4387008013 creator A5013881064 @default.
• W4387008013 creator A5018002301 @default.
• W4387008013 creator A5039349886 @default.
• W4387008013 creator A5043405626 @default.
• W4387008013 creator A5053637071 @default.
• W4387008013 creator A5057097309 @default.
• W4387008013 creator A5063562796 @default.
• W4387008013 creator A5063666874 @default.
• W4387008013 date "2024-01-01" @default.
• W4387008013 modified "2023-09-30" @default.
• W4387008013 title "Enhanced dissolution of galactomannan and highly efficient selenium functionalization using ionic liquids with dual roles as solvents and catalysts" @default.
• W4387008013 cites W1865897646 @default.
• W4387008013 cites W1983412122 @default.
• W4387008013 cites W1984176123 @default.
• W4387008013 cites W1985412264 @default.
• W4387008013 cites W2013191594 @default.
• W4387008013 cites W2049536332 @default.
• W4387008013 cites W2059653485 @default.
• W4387008013 cites W2076598881 @default.
• W4387008013 cites W2077098132 @default.
• W4387008013 cites W2104919283 @default.
• W4387008013 cites W2118064770 @default.
• W4387008013 cites W2132525235 @default.
• W4387008013 cites W2148284063 @default.
• W4387008013 cites W2165580199 @default.
• W4387008013 cites W2193546524 @default.
• W4387008013 cites W2325879311 @default.
• W4387008013 cites W2389518335 @default.
• W4387008013 cites W2522902805 @default.
• W4387008013 cites W2587825210 @default.
• W4387008013 cites W2591159215 @default.
• W4387008013 cites W2612588066 @default.
• W4387008013 cites W2692515715 @default.
• W4387008013 cites W2884413106 @default.
• W4387008013 cites W2893922229 @default.
• W4387008013 cites W2901974110 @default.
• W4387008013 cites W2913649327 @default.
• W4387008013 cites W2932940321 @default.
• W4387008013 cites W2953835190 @default.
• W4387008013 cites W2972671588 @default.
• W4387008013 cites W2973240312 @default.
• W4387008013 cites W2979795026 @default.
• W4387008013 cites W2981826970 @default.
• W4387008013 cites W2983854474 @default.
• W4387008013 cites W2990309629 @default.
• W4387008013 cites W3006732177 @default.
• W4387008013 cites W3032472748 @default.
• W4387008013 cites W3048486975 @default.
• W4387008013 cites W3130797151 @default.
• W4387008013 cites W3195588649 @default.
• W4387008013 cites W4210345427 @default.
• W4387008013 cites W4210370823 @default.
• W4387008013 cites W4233998925 @default.
• W4387008013 cites W4318478936 @default.
• W4387008013 cites W626769280 @default.
• W4387008013 doi "https://doi.org/10.1016/j.carbpol.2023.121421" @default.
• W4387008013 hasPublicationYear "2024" @default.
• W4387008013 type Work @default.
• W4387008013 citedByCount "0" @default.
• W4387008013 crossrefType "journal-article" @default.
• W4387008013 hasAuthorship W4387008013A5004082387 @default.
• W4387008013 hasAuthorship W4387008013A5007613197 @default.
• W4387008013 hasAuthorship W4387008013A5008600174 @default.
• W4387008013 hasAuthorship W4387008013A5013881064 @default.
• W4387008013 hasAuthorship W4387008013A5018002301 @default.
• W4387008013 hasAuthorship W4387008013A5039349886 @default.
• W4387008013 hasAuthorship W4387008013A5043405626 @default.
• W4387008013 hasAuthorship W4387008013A5053637071 @default.
• W4387008013 hasAuthorship W4387008013A5057097309 @default.
• W4387008013 hasAuthorship W4387008013A5063562796 @default.
• W4387008013 hasAuthorship W4387008013A5063666874 @default.
• W4387008013 hasConcept C100817775 @default.
• W4387008013 hasConcept C112887158 @default.
• W4387008013 hasConcept C115537861 @default.
• W4387008013 hasConcept C127413603 @default.
• W4387008013 hasConcept C145148216 @default.
• W4387008013 hasConcept C147789679 @default.
• W4387008013 hasConcept C154881586 @default.
• W4387008013 hasConcept C161790260 @default.
• W4387008013 hasConcept C166950319 @default.
• W4387008013 hasConcept C178790620 @default.
• W4387008013 hasConcept C185592680 @default.
• W4387008013 hasConcept C21951064 @default.
• W4387008013 hasConcept C2780782397 @default.
• W4387008013 hasConcept C30095370 @default.
• W4387008013 hasConcept C32909587 @default.
• W4387008013 hasConcept C42360764 @default.
• W4387008013 hasConcept C75079739 @default.
• W4387008013 hasConcept C88380143 @default.
• W4387008013 hasConceptScore W4387008013C100817775 @default.
• W4387008013 hasConceptScore W4387008013C112887158 @default.
• W4387008013 hasConceptScore W4387008013C115537861 @default.
• W4387008013 hasConceptScore W4387008013C127413603 @default.

• next