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- W4387012105 abstract "Two epoxidation catalysts, one of which consists of two VANOL ligands and an aluminum and the other that consists of two VANOL ligands and a boron, were compared. Both catalysts are highly effective in the catalytic asymmetric epoxidation of a variety of aromatic and aliphatic aldehydes with diazoacetamides, giving high yields and excellent asymmetric inductions. The aluminum catalyst is effective at 0 °C and the boron catalyst at −40 °C. Although both the aluminum and boron catalysts of (R)-VANOL give very high asymmetric inductions (up to 99% ee), they give opposite enantiomers of the epoxide. The mechanism, rate- and enantioselectivity-determining step, and origin of enantiodivergence are evaluated using density functional theory calculations." @default.
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- W4387012105 date "2023-09-25" @default.
- W4387012105 modified "2023-10-13" @default.
- W4387012105 title "A Lewis Acid-Controlled Enantiodivergent Epoxidation of Aldehydes" @default.
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- W4387012105 doi "https://doi.org/10.1021/acscatal.3c03929" @default.
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