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- W4387012994 abstract "Abstract Vanadate glasses exhibit semiconducting property at certain temperatures. This work demonstrates the conductivity of the composition 45V 2 O 5 –25B 2 O 3 –30P 2 O 5 , which is a new glass in the vanadium-boron-phosphorus ternary system that expands the glass forming area reported in literature data. The glass was obtained through a classical melt-quenching technique. The structural composition of the obtained glass was revealed with Raman spectroscopy and the amorphous characteristic has been highlighted with X-ray diffraction. The characteristic temperatures and the thermal expansion coefficient were determined by dilatometry. Based on the experimental measurements of electrical resistance, mathematical calculations were performed, resulting in a conductivity of 2.04·10 −6 S/cm at 125 °C, and an activation energy of 42.91 kJ/mol for this glass. Impedance spectroscopy in DC and AC at 100 V and 100 Hz to 2 MHz, respectively, showed a lower activation energy of about 0.166 eV and transition temperatures of 24 °C and 11 °C, respectively. These results were compared with those from the literature considering the temperatures at which the reported conductivities were measured. This glass has potential applications in electronic devices and temperature sensors." @default.
- W4387012994 created "2023-09-26" @default.
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- W4387012994 date "2023-09-25" @default.
- W4387012994 modified "2023-09-28" @default.
- W4387012994 title "Obtaining and conductive properties of a vanadate-borate-phosphate glass" @default.
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- W4387012994 doi "https://doi.org/10.1038/s41598-023-43302-8" @default.
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