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- W4387016989 abstract "Preparing AEMs with robust mechanical properties, high ionic conductivity and excellent chemical stability is challenging. Here, cross-linked/aggregated AEMs are prepared by incorporating hydrophilic Jeffamine cross-linkers and hydrophobic side chains into the rigid quaternized poly (vinyl benzyl chloride). Jeffamine's flexibility ensures high elongation at break of the cross-linked/aggregated membranes (125.0–199.8%). The hydrophobic side chain limits excessive water absorption and facilitates self-aggregation of hydrophilic and hydrophobic domains, enhancing tensile strength (5.08–7.40 Mpa in wet state) and improving ionic conductivity of the AEMs (73.8–110.4 mS cm−1 at 80 °C). Alkali-resistant PVB, restricted dimensionality, and ordered micro-phase separation morphology contribute to outstanding chemical stability of the AEMs. Degradation of both backbones and cations is <20% after treatment in 1 M NaOH solution at 80 °C for 30 days. Based on the membrane, a peak power density of 354.4 mW cm−2 at 60 °C is yielded." @default.
- W4387016989 created "2023-09-26" @default.
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- W4387016989 date "2023-09-01" @default.
- W4387016989 modified "2023-10-14" @default.
- W4387016989 title "Alkali-resistant poly (vinyl benzyl chloride) based anion exchange membranes with outstanding flexibility and high hydroxide ion conductivity" @default.
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- W4387016989 doi "https://doi.org/10.1016/j.ijhydene.2023.09.082" @default.
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