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• W4387029351 abstract "CF3-substituted imidoyl sulfoxonium ylides (TFISYs) are extraordinarily versatile and powerful synthons for use in cyclization chemistry that affords diverse CF3-substituted N-heterocycles. We first reacted TFISYs as a two-atom synthon with readily available azoalkenes and then subjected the products to metal-free formal (4+2) cycloaddition chemistry. This protocol features mild conditions and broad substrate scope, is simple to operate, and provides highly functionalized trifluoromethylpyridazines that are widely found in bioactive molecules." @default.
• W4387029351 created "2023-09-26" @default.
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• W4387029351 date "2023-01-01" @default.
• W4387029351 modified "2023-10-18" @default.
• W4387029351 title "Formal (4+2) cycloaddition of azoalkenes with trifluoromethylimidoyl sulfoxonium ylides: synthesis of trifluoromethyl pyridazine derivatives" @default.
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• W4387029351 doi "https://doi.org/10.1039/d3cc03950a" @default.
• W4387029351 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37786379" @default.
• W4387029351 hasPublicationYear "2023" @default.
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