FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387048367> ?p ?o ?g. }

• W4387048367 endingPage "1428" @default.
• W4387048367 startingPage "1428" @default.
• W4387048367 abstract "The Neutral to Ionic phase Transition (NIT) that occurs in few mixed stack charge transfer cocrystals at high pressure or low temperature is a charge instability combined with a structural instability. The lattice contraction, which increases the 3D Coulomb interactions, favors a higher degree of charge transfer. Due to Peierls instability, this leads to the dimerization of the stack, breaking its inversion symmetry. The 3D interactions also determine the arrangement of the adjacent dimerized polar stacks, making the ionic phase ferroelectric or antiferroelectric. The role of these parameters that modulate the NIT has been widely studied in Tetrathiafulvalene-haloquinone cocrystals. Here, we compare the high-pressure behavior of three of them: the newly synthesized TTF-FA and DMTTF-FA with the known DMTTF-CA and isostructural DMTTF-FA. We followed the evolution of the lattice phonons via THz Raman spectroscopy, assessing the pressure-dependent structural changes. While the FA-based crystals undergo strong first-order NIT, DMTTF-CA shows a continuous transition. The high-pressure behavior of each crystal is also compared with the low-temperature behavior." @default.
• W4387048367 created "2023-09-27" @default.
• W4387048367 creator A5037263169 @default.
• W4387048367 creator A5050394698 @default.
• W4387048367 creator A5082680834 @default.
• W4387048367 date "2023-09-26" @default.
• W4387048367 modified "2023-09-27" @default.
• W4387048367 title "Pressure-Induced Neutral to Ionic Phase Transition in TTF-Fluoranil, DimethylTTF-Fluoranil and DimethylTTF-Chloranil: A Comparative THz Raman Study" @default.
• W4387048367 cites W1965470724 @default.
• W4387048367 cites W1969360633 @default.
• W4387048367 cites W1971012317 @default.
• W4387048367 cites W1997126459 @default.
• W4387048367 cites W2002272388 @default.
• W4387048367 cites W2020766681 @default.
• W4387048367 cites W2022489179 @default.
• W4387048367 cites W2024741097 @default.
• W4387048367 cites W2024880963 @default.
• W4387048367 cites W2026065731 @default.
• W4387048367 cites W2034138730 @default.
• W4387048367 cites W2044761771 @default.
• W4387048367 cites W2055526780 @default.
• W4387048367 cites W2058325847 @default.
• W4387048367 cites W2059506264 @default.
• W4387048367 cites W2075554062 @default.
• W4387048367 cites W2087763550 @default.
• W4387048367 cites W2106360369 @default.
• W4387048367 cites W2606500720 @default.
• W4387048367 cites W2606564389 @default.
• W4387048367 cites W2922804438 @default.
• W4387048367 cites W3134819199 @default.
• W4387048367 cites W4226453610 @default.
• W4387048367 doi "https://doi.org/10.3390/cryst13101428" @default.
• W4387048367 hasPublicationYear "2023" @default.
• W4387048367 type Work @default.
• W4387048367 citedByCount "0" @default.
• W4387048367 crossrefType "journal-article" @default.
• W4387048367 hasAuthorship W4387048367A5037263169 @default.
• W4387048367 hasAuthorship W4387048367A5050394698 @default.
• W4387048367 hasAuthorship W4387048367A5082680834 @default.
• W4387048367 hasBestOaLocation W43870483671 @default.
• W4387048367 hasConcept C115624301 @default.
• W4387048367 hasConcept C120665830 @default.
• W4387048367 hasConcept C121332964 @default.
• W4387048367 hasConcept C133386390 @default.
• W4387048367 hasConcept C145148216 @default.
• W4387048367 hasConcept C149288129 @default.
• W4387048367 hasConcept C159467904 @default.
• W4387048367 hasConcept C178790620 @default.
• W4387048367 hasConcept C185592680 @default.
• W4387048367 hasConcept C192562407 @default.
• W4387048367 hasConcept C205188671 @default.
• W4387048367 hasConcept C207821765 @default.
• W4387048367 hasConcept C2182769 @default.
• W4387048367 hasConcept C24169881 @default.
• W4387048367 hasConcept C26873012 @default.
• W4387048367 hasConcept C2778421084 @default.
• W4387048367 hasConcept C32909587 @default.
• W4387048367 hasConcept C40003534 @default.
• W4387048367 hasConcept C49040817 @default.
• W4387048367 hasConcept C57879066 @default.
• W4387048367 hasConcept C79090758 @default.
• W4387048367 hasConcept C8010536 @default.
• W4387048367 hasConceptScore W4387048367C115624301 @default.
• W4387048367 hasConceptScore W4387048367C120665830 @default.
• W4387048367 hasConceptScore W4387048367C121332964 @default.
• W4387048367 hasConceptScore W4387048367C133386390 @default.
• W4387048367 hasConceptScore W4387048367C145148216 @default.
• W4387048367 hasConceptScore W4387048367C149288129 @default.
• W4387048367 hasConceptScore W4387048367C159467904 @default.
• W4387048367 hasConceptScore W4387048367C178790620 @default.
• W4387048367 hasConceptScore W4387048367C185592680 @default.
• W4387048367 hasConceptScore W4387048367C192562407 @default.
• W4387048367 hasConceptScore W4387048367C205188671 @default.
• W4387048367 hasConceptScore W4387048367C207821765 @default.
• W4387048367 hasConceptScore W4387048367C2182769 @default.
• W4387048367 hasConceptScore W4387048367C24169881 @default.
• W4387048367 hasConceptScore W4387048367C26873012 @default.
• W4387048367 hasConceptScore W4387048367C2778421084 @default.
• W4387048367 hasConceptScore W4387048367C32909587 @default.
• W4387048367 hasConceptScore W4387048367C40003534 @default.
• W4387048367 hasConceptScore W4387048367C49040817 @default.
• W4387048367 hasConceptScore W4387048367C57879066 @default.
• W4387048367 hasConceptScore W4387048367C79090758 @default.
• W4387048367 hasConceptScore W4387048367C8010536 @default.
• W4387048367 hasIssue "10" @default.
• W4387048367 hasLocation W43870483671 @default.
• W4387048367 hasOpenAccess W4387048367 @default.
• W4387048367 hasPrimaryLocation W43870483671 @default.
• W4387048367 hasRelatedWork W1668668558 @default.
• W4387048367 hasRelatedWork W1965227667 @default.
• W4387048367 hasRelatedWork W2023266934 @default.
• W4387048367 hasRelatedWork W2050775256 @default.
• W4387048367 hasRelatedWork W2059021401 @default.
• W4387048367 hasRelatedWork W2318250919 @default.
• W4387048367 hasRelatedWork W2998167335 @default.
• W4387048367 hasRelatedWork W3029527023 @default.
• W4387048367 hasRelatedWork W3142207692 @default.
• W4387048367 hasRelatedWork W2467809990 @default.

• next