Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387063621> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W4387063621 endingPage "125145" @default.
- W4387063621 startingPage "125145" @default.
- W4387063621 abstract "The microporosity of hypercrosslinked polymers (HCPs) renders such materials ideal adsorbents for carbon capture. We recently showed that the CO2/N2 selectivity of HCPs synthesised by internal crosslinking of poly-α,α′-dichloro-p-xylene (p-DCX) in continuous flow synthesis was 850 % higher than those produced in batch reactions. We hypothesised that this could potentially reduce the amount of HCP adsorbents required for delivering the same carbon capture performances, hence improving the environmental impacts of carbon capture. This was evaluated here where we analysed the environmental impacts of using both batch- and flow-synthesised HCPs for adsorbing 40 mg of CO2 with the life-cycle assessment method. We also deployed this approach to evaluate HCPs synthesised via post-crosslinking of polystyrene crosslinked with DCX (p-PS-DCX) and externally crosslinking of polystyrene with formaldehyde dimethyl acetal (FDA) crosslinker (p-PS-FDA). Amongst all HCPs studied in this work, the changes in environmental impact of deploying internally crosslinked HCPs for carbon capture were the worst. This was mostly attributed to its low product yield (7 %), which had a larger influence on the environmental impacts than its adsorption performance as verified by sensitivity analysis. To offset the adverse effects of low product yield, the product yield from flow synthesis of HCPs should ideally reach 25 %. By identifying that product yield is key for promoting environmental sustainability in carbon capture using flow-derived HCPs, future work should focus on optimising continuous flow synthesis to deliver ideal product yield." @default.
- W4387063621 created "2023-09-27" @default.
- W4387063621 creator A5009669683 @default.
- W4387063621 creator A5064062665 @default.
- W4387063621 date "2024-01-01" @default.
- W4387063621 modified "2023-10-03" @default.
- W4387063621 title "Assessing the environmental impacts of flow and batch syntheses of hypercrosslinked polymers for low-pressure CO2 adsorption" @default.
- W4387063621 cites W1745023698 @default.
- W4387063621 cites W1992844372 @default.
- W4387063621 cites W2001890098 @default.
- W4387063621 cites W2021577233 @default.
- W4387063621 cites W2040421070 @default.
- W4387063621 cites W2067857090 @default.
- W4387063621 cites W2087696107 @default.
- W4387063621 cites W2112358649 @default.
- W4387063621 cites W2132851543 @default.
- W4387063621 cites W2290429661 @default.
- W4387063621 cites W2566055581 @default.
- W4387063621 cites W2590177458 @default.
- W4387063621 cites W2755036927 @default.
- W4387063621 cites W2765242096 @default.
- W4387063621 cites W2770211073 @default.
- W4387063621 cites W2770532251 @default.
- W4387063621 cites W2894543062 @default.
- W4387063621 cites W2896985869 @default.
- W4387063621 cites W2903359934 @default.
- W4387063621 cites W2913884351 @default.
- W4387063621 cites W2952062786 @default.
- W4387063621 cites W2971468329 @default.
- W4387063621 cites W2981289524 @default.
- W4387063621 cites W2985065154 @default.
- W4387063621 cites W3013195375 @default.
- W4387063621 cites W3081686376 @default.
- W4387063621 cites W3119810453 @default.
- W4387063621 cites W3135042623 @default.
- W4387063621 cites W3198448046 @default.
- W4387063621 cites W3216071190 @default.
- W4387063621 cites W3217316521 @default.
- W4387063621 cites W4200094503 @default.
- W4387063621 cites W4200237152 @default.
- W4387063621 cites W4205206499 @default.
- W4387063621 cites W4220674885 @default.
- W4387063621 cites W4319996572 @default.
- W4387063621 cites W4379468438 @default.
- W4387063621 cites W4379599104 @default.
- W4387063621 doi "https://doi.org/10.1016/j.seppur.2023.125145" @default.
- W4387063621 hasPublicationYear "2024" @default.
- W4387063621 type Work @default.
- W4387063621 citedByCount "0" @default.
- W4387063621 crossrefType "journal-article" @default.
- W4387063621 hasAuthorship W4387063621A5009669683 @default.
- W4387063621 hasAuthorship W4387063621A5064062665 @default.
- W4387063621 hasBestOaLocation W43870636211 @default.
- W4387063621 hasConcept C127413603 @default.
- W4387063621 hasConcept C134121241 @default.
- W4387063621 hasConcept C150394285 @default.
- W4387063621 hasConcept C159985019 @default.
- W4387063621 hasConcept C178790620 @default.
- W4387063621 hasConcept C185592680 @default.
- W4387063621 hasConcept C192562407 @default.
- W4387063621 hasConcept C21880701 @default.
- W4387063621 hasConcept C2777922577 @default.
- W4387063621 hasConcept C42360764 @default.
- W4387063621 hasConcept C521977710 @default.
- W4387063621 hasConceptScore W4387063621C127413603 @default.
- W4387063621 hasConceptScore W4387063621C134121241 @default.
- W4387063621 hasConceptScore W4387063621C150394285 @default.
- W4387063621 hasConceptScore W4387063621C159985019 @default.
- W4387063621 hasConceptScore W4387063621C178790620 @default.
- W4387063621 hasConceptScore W4387063621C185592680 @default.
- W4387063621 hasConceptScore W4387063621C192562407 @default.
- W4387063621 hasConceptScore W4387063621C21880701 @default.
- W4387063621 hasConceptScore W4387063621C2777922577 @default.
- W4387063621 hasConceptScore W4387063621C42360764 @default.
- W4387063621 hasConceptScore W4387063621C521977710 @default.
- W4387063621 hasFunder F4320324523 @default.
- W4387063621 hasLocation W43870636211 @default.
- W4387063621 hasOpenAccess W4387063621 @default.
- W4387063621 hasPrimaryLocation W43870636211 @default.
- W4387063621 hasRelatedWork W2047888616 @default.
- W4387063621 hasRelatedWork W2062749443 @default.
- W4387063621 hasRelatedWork W2075861635 @default.
- W4387063621 hasRelatedWork W2401463829 @default.
- W4387063621 hasRelatedWork W2533770197 @default.
- W4387063621 hasRelatedWork W2748952813 @default.
- W4387063621 hasRelatedWork W2899084033 @default.
- W4387063621 hasRelatedWork W2949184651 @default.
- W4387063621 hasRelatedWork W2950847194 @default.
- W4387063621 hasRelatedWork W2952649848 @default.
- W4387063621 hasVolume "329" @default.
- W4387063621 isParatext "false" @default.
- W4387063621 isRetracted "false" @default.
- W4387063621 workType "article" @default.