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• W4387067648 abstract "A novel and convenient method for the N-formylation reaction of amines with DMF as a formylating agent has been developed, utilizing a catalytic amount of diethyl phosphite/imidazole. Diethyl phosphite, as a nucleophilic catalyst, plays a significant role in this conversion. The presented method has a broad substrate scope, and various N-formyl products were obtained in good to excellent yields. Moreover, by using DMA instead of DMF, the N-acetylation reaction was also successful. The reaction of o-phenylenediamines with DMF afforded the corresponding benzimidazoles. Furthermore, N-sulfonyl amidines were obtained in good to excellent yields by the reaction of sulfonamides with DMF under similar conditions." @default.
• W4387067648 created "2023-09-27" @default.
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• W4387067648 date "2023-01-01" @default.
• W4387067648 modified "2023-10-05" @default.
• W4387067648 title "Phosphite-Imidazole Catalyzed N-Formylation and N-Acylation of Amines" @default.
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• W4387067648 doi "https://doi.org/10.1039/d3ob01306e" @default.
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• W4387067648 hasPublicationYear "2023" @default.
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