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- W4387071919 endingPage "107853" @default.
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- W4387071919 abstract "[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is extensively applied as the electron transport layer (ETL) in CH3NH3PbI3-based solar cells, but it is expensive and hygroscopic in the atmosphere. ZnO is cheap and air-stable, but the reaction between ZnO and CH3NH3PbI3 generally causes the degradation of the latter. In this paper, ZnO-embedded PCBM (ZPCBM) ETLs were prepared by spin-coating the ZnO nanograin dispersion mixed with the PCBM precursor solution in an optimal volume ratio of 1:3. Embedded ZnO nanograins enhance the electron extraction ability and the hydrophobicity of the PCBM matrix, while the amorphous PCBM matrix reduces the direct contact between ZnO nanograins and the CH3NH3PbI3 absorption layer, thus depressing the reaction between them. As a result, the un-encapsulated ZPCBM/CH3NH3PbI3/NiO solar cell exhibits a high PCE of 19.21% and an open circuit voltage of 1.07 V. After exposure to the atmosphere for 1008 h, it retains 90% of the initial PCE, showing a greatly improved air stability compared with CH3NH3PbI3 solar cells with the PCBM or ZnO ETL." @default.
- W4387071919 created "2023-09-27" @default.
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- W4387071919 date "2023-12-01" @default.
- W4387071919 modified "2023-10-17" @default.
- W4387071919 title "Highly air-stable and efficient CH3NH3PbI3 solar cells enhanced by ZnO-embedded PCBM electron transport layers" @default.
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- W4387071919 doi "https://doi.org/10.1016/j.mssp.2023.107853" @default.
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