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- W4387078110 endingPage "14972" @default.
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- W4387078110 abstract "Conversion of steel industry off-gases to value-added chemicals enabled by renewable electricity can significantly reduce the environmental burden of the steelmaking process. Herein, we demonstrate that CO2 reduction by H2, both contained in steel mill off-gases, to form syngas via the reverse water-gas-shift reaction is effectively performed by nanosecond pulsed discharges at atmospheric pressure. The experimental results suggest the following: (i) An optimum interelectrode distance exists, maximizing CO2 conversion. (ii) CO2 conversion at constant SEI follows a nonmonotonic trend with H2 excess. CO2 conversion increases with H2 excess up to H2:CO2 = 3:1 upon shifting the chemical equilibrium. At larger H2:CO2, both gas cooling, promoted by the high H2 content, and hindered CO2 collisions in a highly diluted stream hamper CO2 conversion. (iii) SEI enhances CO2 conversion, but the effect decreases with increasing SEI due to equilibrium limitations. A stoichiometric H2:CO2 feed ratio in the plasma reactor is recommended for higher energy efficiency. Intensifying MeOH productivity via SEI elevation is not advised as a 2-fold SEI increase results only in 17% higher MeOH throughput." @default.
- W4387078110 created "2023-09-28" @default.
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- W4387078110 date "2023-09-27" @default.
- W4387078110 modified "2023-10-13" @default.
- W4387078110 title "Valorizing the Steel Industry Off-Gases: Proof of Concept and Plantwide Design of an Electrified and Catalyst-Free Reverse Water–Gas-Shift-Based Route to Methanol" @default.
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- W4387078110 doi "https://doi.org/10.1021/acs.est.3c05246" @default.
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