FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387078980> ?p ?o ?g. }

• W4387078980 endingPage "115181" @default.
• W4387078980 startingPage "115181" @default.
• W4387078980 abstract "In the current study, we have chosen a highly fluorescent laser dye called pyrromethene 650 (PM-650) to investigate its photophysical properties using theoretical and experimental methods. We measured the absorption and emission spectra of PM-650 in polar protic and polar aprotic solvents at ambient temperature. Bathochromic and hypsochromic shifts were observed in the absorption and fluorescence spectra of the laser dye, confirming the presence of transitions between π → π* and n → π* states. We further estimated the ground and excited state dipole moments of PM-650 through experimental (solvatochromic correlations) and theoretical (ab initio) techniques, and compared the results. Interestingly, The PM-650 displayed an increased excited state dipole moment when contrasted with its ground state. Furthermore, using the B3LYP/6-311G++(d, p) approach, we estimated the natural bond orbital and molecular electrostatic potential map of PM-650 and discussed the results. Additionally, we theoretically determined the HOMO-LUMO energy band gap of PM-650 in different solvents with varying polarities, and found good agreement with the experimentally obtained values. To assess the reactivity and softness of PM-650, we calculated global chemical reactive descriptor values based on the theoretically estimated HOMO-LUMO. Our results suggest that PM-650 is highly reactive and possesses a soft nature." @default.
• W4387078980 created "2023-09-28" @default.
• W4387078980 creator A5025014163 @default.
• W4387078980 creator A5066030990 @default.
• W4387078980 creator A5069574460 @default.
• W4387078980 creator A5073460991 @default.
• W4387078980 creator A5092950853 @default.
• W4387078980 date "2024-01-01" @default.
• W4387078980 modified "2023-10-18" @default.
• W4387078980 title "Systematic photophysical investigation on pyrromethene 650 laser dye: Experimental and DFT approach" @default.
• W4387078980 cites W1963531832 @default.
• W4387078980 cites W1980384899 @default.
• W4387078980 cites W1993327079 @default.
• W4387078980 cites W1993612334 @default.
• W4387078980 cites W2003272298 @default.
• W4387078980 cites W2004167046 @default.
• W4387078980 cites W2005936128 @default.
• W4387078980 cites W2011349168 @default.
• W4387078980 cites W2021023453 @default.
• W4387078980 cites W2035472763 @default.
• W4387078980 cites W2038767330 @default.
• W4387078980 cites W2039106845 @default.
• W4387078980 cites W2059635855 @default.
• W4387078980 cites W2069007845 @default.
• W4387078980 cites W2071922898 @default.
• W4387078980 cites W2076886379 @default.
• W4387078980 cites W2079507386 @default.
• W4387078980 cites W2081259636 @default.
• W4387078980 cites W2085901983 @default.
• W4387078980 cites W2108387238 @default.
• W4387078980 cites W2122442510 @default.
• W4387078980 cites W2132905138 @default.
• W4387078980 cites W2147754519 @default.
• W4387078980 cites W2171538327 @default.
• W4387078980 cites W2495081881 @default.
• W4387078980 cites W2772408871 @default.
• W4387078980 cites W3091571782 @default.
• W4387078980 cites W4239335574 @default.
• W4387078980 cites W4307445935 @default.
• W4387078980 doi "https://doi.org/10.1016/j.jphotochem.2023.115181" @default.
• W4387078980 hasPublicationYear "2024" @default.
• W4387078980 type Work @default.
• W4387078980 citedByCount "0" @default.
• W4387078980 crossrefType "journal-article" @default.
• W4387078980 hasAuthorship W4387078980A5025014163 @default.
• W4387078980 hasAuthorship W4387078980A5066030990 @default.
• W4387078980 hasAuthorship W4387078980A5069574460 @default.
• W4387078980 hasAuthorship W4387078980A5073460991 @default.
• W4387078980 hasAuthorship W4387078980A5092950853 @default.
• W4387078980 hasConcept C119824511 @default.
• W4387078980 hasConcept C120665830 @default.
• W4387078980 hasConcept C121332964 @default.
• W4387078980 hasConcept C125287762 @default.
• W4387078980 hasConcept C139358910 @default.
• W4387078980 hasConcept C14158195 @default.
• W4387078980 hasConcept C159985019 @default.
• W4387078980 hasConcept C173523689 @default.
• W4387078980 hasConcept C17814232 @default.
• W4387078980 hasConcept C178790620 @default.
• W4387078980 hasConcept C181500209 @default.
• W4387078980 hasConcept C184779094 @default.
• W4387078980 hasConcept C185592680 @default.
• W4387078980 hasConcept C192562407 @default.
• W4387078980 hasConcept C2781442258 @default.
• W4387078980 hasConcept C32909587 @default.
• W4387078980 hasConcept C46051903 @default.
• W4387078980 hasConcept C520434653 @default.
• W4387078980 hasConcept C60760409 @default.
• W4387078980 hasConcept C67218372 @default.
• W4387078980 hasConcept C69523127 @default.
• W4387078980 hasConcept C75473681 @default.
• W4387078980 hasConcept C91881484 @default.
• W4387078980 hasConceptScore W4387078980C119824511 @default.
• W4387078980 hasConceptScore W4387078980C120665830 @default.
• W4387078980 hasConceptScore W4387078980C121332964 @default.
• W4387078980 hasConceptScore W4387078980C125287762 @default.
• W4387078980 hasConceptScore W4387078980C139358910 @default.
• W4387078980 hasConceptScore W4387078980C14158195 @default.
• W4387078980 hasConceptScore W4387078980C159985019 @default.
• W4387078980 hasConceptScore W4387078980C173523689 @default.
• W4387078980 hasConceptScore W4387078980C17814232 @default.
• W4387078980 hasConceptScore W4387078980C178790620 @default.
• W4387078980 hasConceptScore W4387078980C181500209 @default.
• W4387078980 hasConceptScore W4387078980C184779094 @default.
• W4387078980 hasConceptScore W4387078980C185592680 @default.
• W4387078980 hasConceptScore W4387078980C192562407 @default.
• W4387078980 hasConceptScore W4387078980C2781442258 @default.
• W4387078980 hasConceptScore W4387078980C32909587 @default.
• W4387078980 hasConceptScore W4387078980C46051903 @default.
• W4387078980 hasConceptScore W4387078980C520434653 @default.
• W4387078980 hasConceptScore W4387078980C60760409 @default.
• W4387078980 hasConceptScore W4387078980C67218372 @default.
• W4387078980 hasConceptScore W4387078980C69523127 @default.
• W4387078980 hasConceptScore W4387078980C75473681 @default.
• W4387078980 hasConceptScore W4387078980C91881484 @default.
• W4387078980 hasLocation W43870789801 @default.
• W4387078980 hasOpenAccess W4387078980 @default.
• W4387078980 hasPrimaryLocation W43870789801 @default.

• next