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- W4387079058 endingPage "112390" @default.
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- W4387079058 abstract "Cobalt microperoxidase-11 (CoMP11-Ac) is a cobalt porphyrin-peptide catalyst for hydrogen (H2) evolution from water. Herein, we assess electrocatalytic activity of CoMP11-Ac from pH 1.0–10.0. This catalyst remains intact and active under highly acidic conditions (pH 1.0) that are desirable for maximizing H2 evolution activity. Analysis of electrochemical data indicate that H2 evolution takes place by two pH-dependent mechanisms. At pH < 4.3, a proton transfer mechanism involving the propionic acid groups of the porphyrin is proposed, decreasing the catalytic overpotential by 280 mV." @default.
- W4387079058 created "2023-09-28" @default.
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- W4387079058 date "2023-12-01" @default.
- W4387079058 modified "2023-10-08" @default.
- W4387079058 title "Hydrogen evolution catalysis by a cobalt porphyrin peptide: A proposed role for porphyrin propionic acid groups" @default.
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- W4387079058 doi "https://doi.org/10.1016/j.jinorgbio.2023.112390" @default.
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