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• W4387079082 abstract "Multicomponent zirconate solid solutions A2Zr2O7 (A= (Sm,Yb), (Sm,Yb,Gd), (Sm,Yb,Gd,Er), and (Sm,Yb,Gd,Er,Dy)) were synthesized through spark plasma sintering and their chemical durability was investigated via semi-dynamic leaching tests in pH = 1 nitric acid at 90 °C. Incongruent dissolution occurred for all samples with the preferential elemental release of zirconium in all A2Zr2O7 except for high entropy (Sm,Yb,Gd,Er,Dy)Zr2O7 which displays a congruent release of the A-site elements and Zr. A strong positive correlation was found between the lanthanide elemental release rates and the A-site cation size disorder, whereas a negative correlation was observed between the elemental release rates and mixing entropy." @default.
• W4387079082 created "2023-09-28" @default.
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• W4387079082 date "2023-09-01" @default.
• W4387079082 modified "2023-10-07" @default.
• W4387079082 title "Chemical durability of multicomponent lanthanide zirconate solid solutions" @default.
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• W4387079082 doi "https://doi.org/10.1016/j.ceramint.2023.09.263" @default.
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