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- W4387093555 abstract "Spiro-orthoesters, produced from the coupling of lactones and epoxides, are presequenced monomers capable of generating alternating poly(ether-alt-esters) after ring-opening polymerization. Recently, we reported the selective synthesis of spiro-orthoesters through the coupling of epoxides and lactones catalyzed by a cationic alkyl indium catalyst. Herein, we investigate the mechanism of this reaction using structure–function relationships and computational studies. We show that this reaction is governed by Michaelis–Menten-type saturation kinetics, which, along with the low Lewis acidity of these indium catalysts, explains their selectivity." @default.
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- W4387093555 date "2023-09-27" @default.
- W4387093555 modified "2023-09-28" @default.
- W4387093555 title "Mechanistic Insights into Selective Indium-Catalyzed Coupling of Epoxides and Lactones" @default.
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- W4387093555 doi "https://doi.org/10.1021/acscatal.3c03450" @default.
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